6 Problem Solved - Organic Chemistry I - Exam 1 | CHEM 3311, Exams of Organic Chemistry

Download 6 Problem Solved - Organic Chemistry I - Exam 1 | CHEM 3311 and more Exams Organic Chemistry in PDF only on Docsity! Problem 1. (40 points) Give the final products for the following reactions. If no reaction occurs, state so. Be sure to show the correct stereochemistry. Circle Your Answer mn iS ccm 1) CHMgBr(excess/THE pD é- <u + ity nu 2) H,0* uy (44 ) (+!) i 1) LAH /THE : B) COs mo Cid eo tH at (44) (Fh) CHg n ° Gs) © o 6. GEN CHy > CHCA, cf c= HCH, [ H,0 D 7 G) D) neo can —es cH yoy CH, 4 WHY i et (+4) GH) Oo 9 Ww cy Ww = ats ° (pHi ees CLS eed (43) (+2) ¢H)-CHScHy 1) LDA, THF — - fe eee eae = +S ° Co 2) CE=CH-CHBr coy 7 ¢ ) o C4) cA o ut CH2Br 1) KCN / acetone ~ me CHa - co}! + Vv rly 2) HO" heat leu (+N) (41) Problem 2 (20 points) For the following reactions determine if the equilibrium lies to the left or to the right as drawn, and circle the appropriate answer. Circle Answer q i ° 9° ll ll Hor "So- cls + CHAOH: He"o~ocHyt HO-o~CH, LEFT wom) 9 New 5 I 6 ll Hyc7""~OEt + NaOH Ho o~o8t + H,0 LEFT RIGHT 9° q ° 1 4 2 no S~o8t hes me Net + BLO ™ 2 + Hee t He LEFT RIGHT 9 9° ° 9 Nat D) I S I ° I pI HyG""“NHp yy yo Ot HyeGw"™—NHe + Hye" Ot LEFT RIGHT 9 Nat 9 t o tl BE) NaNHy + H0O™08t qe Ho CoEt + NH; LOIT fo) ° t A B yo-’~on + SOCL He-~o + SO, +HC! LEFT 9 Nat Nat 9 ° i sf i 1 Ho ENHy HCO CH, HON, OOH” Leer RIGHT © nad 2 9 » 1 Mery tod 6 wee on me Hey no Nat — ‘ican in 29 0 i i . . DHyoTPNHCH, + oon Ho “07 Cs + CHyNH, LEFT RIGHT j i D pom + “oC + AICI LEFT RIGHT }