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Reactions of Alkenes: Types, Mechanisms, and Products, Quizzes of Organic Chemistry

Definitions and mechanisms for various reactions of alkenes, including markovnikov and anti-markovnikov additions, halogenations, hydroboration-oxidation, and oxidation with peroxy acids. Each term includes a definition and a brief description of the reaction.

Typology: Quizzes

2010/2011

Uploaded on 04/20/2011

goalie4eva
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Download Reactions of Alkenes: Types, Mechanisms, and Products and more Quizzes Organic Chemistry in PDF only on Docsity! TERM 1 Alkene + dilute H2SO4 DEFINITION 1 Markinov addition of alcohol and hydrogen. Puts the OH on the more substituted carbon. Not stereospecific TERM 2 Alkene + X2 (cold & dark) DEFINITION 2 Adds a halide to each carbon of the double bond. X is added to opposite sides, so this is an anti addtn. TERM 3 Alkene + X2 + H2O (cold & dark) DEFINITION 3 Adds a halide and alcohol group to the sides of the double bond. Markinov addtn, so the OH is added to the more substituted carbon and the X is added to the less substituted carbon. Its an anti addtn, so the OH and X are added from other sides. TERM 4 Alkene + 1.O3 + 2. H2O + Zn DEFINITION 4 Cleaves the alkene at the double bond and forms C=O where the C=C was on each carbon. CH3CH=CHCH3 becomes CH3CH=O O=CHCH3 TERM 5 Alkene + H2 + Pd DEFINITION 5 Adds two hydrogens to either side of the double bond. H's are added to the same side due to the "spaceship-like" Pd that grabs the H's. (Therefore, this is a syn addtn)
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