Download cheat sheet for acid base that can help you prepare for exams and more Cheat Sheet Chemistry in PDF only on Docsity! Chem 122. Acids problem set Mar 19-24 Names:
Oxtoby Chapter 14 Problems Acids
1) Which of the ap) can behave as Bronsted-Lowry acids in aqueous solution?
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te Ho [ey
HCIO W-Elsgr got + | [ClFO]
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\ HCO)
4 For each of the following acid/base equilibria, predict which side is favored in aqueous
Guple solution containing only the listed species, spectator ions, and water.
CRA bra
agora t a. HN3 +HCO3 —C:00: + Ng (H2COs pKa = 6.35, HNs pKa = 4.63)
‘ pr s Nong aud brite vi L'b
Wee N, Ke Kar von the otter i a
pb QH + HsPOs == Hah Os + 20.
banca” 2 HWe Ge, r TT ge base pushes 25
NN. Nat ee Nyt ra — HCO3'+HF (HF pK = 3.14)
MyC03
a d. evo = CsHsO" + NHg* (CeHsOH pKz = 9.80, NHq* pKa = 9.25)
2
K> Kg
@ Calculate the hydroxide ion concentration, [OH’], of an aqueous solution of 0.314 M
164-62 Co (a weak base with the formula C2HsNHz2). Kp = 4.3 x 10%
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ao” p= 2 Ke +04 HA GH Gueipetanbodae (GNZCH, UH, + Of
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E ORR = ce -
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E xo3t4m AX eo
Chem 122. Acids problem set Mar 19-24 Names:
4) One of your friends claims that they can calculate the pH of a buffer system without
knowing the actual concentrations of the conjugate acid/base pair. Another friend
disagrees, as the equation for calculating the pH explicitly requires concentrations. Who
is correct? Explain, and show the math.
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nerd the rte, ‘
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5) Fora0.1M aqueous solution of each of the following Be is Shar a compound
you could add to the solution below to make njugate acid/base buffer. Which
solutions should maintain a basic (>7) pH? An acidic (<7) pH?
a. ammonium bromide (pKa = 9.4)
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On aud C4n) bare Sa ae
b. CHsCO2H (pK; = 4.8)
20 ae tary
CMC it Nae SS CHZ CK BY cl
Cons base Na OAc .
c. NazHPOg (pKp = 6.8) a eae
Merle, Hpoy StOS ty Hr PO + OH rd y i”
haek Cony acid In FOn
6) What is the pH of a 0.100 M solution of potassium benzoate (CsHsCOOK)? Ka =6.5 E-5
for benzoic acid. i
QC. + Np (2, + ot
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iS 7* *
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