Department of Chemistry Lecture Schedule and Courses of Instruction, Lecture notes of Organic Chemistry

Download Department of Chemistry Lecture Schedule and Courses of Instruction and more Lecture notes Organic Chemistry in PDF only on Docsity! C O R N E L L UNIVERSITY OFFICIAL PUBLICATION Volume X V II Number n The College of Arts and Sciences Announcement of the Department of Chemistry 1926-27 Ithaca, New York Published by the University M ay 1, 1926 D E P A R T M E N T OF C H E M IS T R Y : L E C T U R E SC H E D U LE FIRST TERM Hour M ON. TU E . W ED. T H U R . FR I. SAT. Hour 8 775 505 775 505 8 205 220 205 220 245 9 305 315 305 315 305 9 405 630 405 630 405 525 IO 705 430 705 430 705 10 IOI1 101s IOI1 ior2 IOI1 IOI2 130 415 130 4 i 5 130 i i 250 460 250 460 11 605 605 325 725 805 725 805 725 255 210 255 225 12 375 535 375 520 375 375 12 45° 450 530 SECOND TERM Hour M ON. TU E . W ED. T H U R . FR I. SAT. Hour 8 775 505 775 505 8 205 140 205 140 Q 3°5 220 305 220 305 Q 405 315 405 315 405 640 542 640 542 10 530 430 705 430 705 10 705 776 880 776 880 IOI1 IOI2 IOI1 1022 IOI1 IOI2 130 415 130 415 130 II 250 460 250 460 335 11 7 i 5 615 7 i 5 615 7 i 5 815 81s 235 210 235 225 12 450 450 12 875 550 875 5 20 875 DEPARTMENT OF CHEMISTRY 5 Second Y ear Introductory Organic Chemistry........ Organic Chemistry Laboratory........... Introductory Quantitative Analysis. . Quantitative Analysis Laboratory. . . Introductory Chemical Spectroscopy. Gas and Fuel Analysis......................... Elementary Mineralogy....................... Heat and Light..................................... Magnetism and Electricity.................. Physical Experiments........................... . Chemistry 30s 3 3 Chemistry 310 3 3 . Chemistry 220 3 Chemistry 221 3 — .Chemistry 503 3 . Chemistry 250 4 or 0 0 or 4 . Geology 311 0 or 3 3 or 0 . Physics 31 2 — . Physics 32 — 2 .Physics 14 — 2 Y ear .Chemistry 40s 3 3 . Chemistry 410 3 3 Chemistry 130 3 3 . Chemistry 530 3 — . Chemistry 235 2 . Chemistry 230 — 4 .Physics 14 2 (at least) 4 4 [ Y ear . Chemistry 705 3 3 . Chemistry 905 I . Chemistry 4 4 .Engineering 367 4 .Engineering 417 4 (at least) 6 6 Candidates for the degree of Bachelor of Chemistry are required to take at least eight hours in research during the senior year in a division of the Department to be selected by the student. These divi­ sions are: Inorganic Chemistry (Course 195); Analytical Chemistry (Course 295); Organic Chemistry (Course 395); Physical Chemistry (Course 495); Optical Chemistry (Course 595); Sanitary Chemistry (Course 695); Industrial Chemistry (Course 795); Agricultural Chemistry (Course 895). The elective courses required in the curriculum may be chosen by the student, in each case with the approval of the Department of Chemistry, from the advanced courses in Chemistry, or from certain courses in other departments of the College of Arts and Sciences, or in other colleges of the University. Students in the Course in Chemistry may register for 20 hours a term. To register for more than 20 hours, the student must first secure the consent of the Department. T he Honor C ode in E xaminations Under a constitution proposed and adopted by the students, and approved by the University Faculty on March 9, 1921, all students of Cornell University are put upon their honor with respect to their con­ duct in examinations and in other tests of work by which they are earning academic credit. The students have made themselves re­ sponsible for maintaining the code. For the trial of charges of breach of honor they elect committees of their own— a central committee 6 CORNELL UNIVERSITY for the University, and a committee in each of the colleges. Every student is expected to do his share in upholding the code, not only by honorable conduct on his own part, but also by refusal to conceal or condone fraud on another’s part. A fraud observed in any college should be reported to a member of the student honor Committee of that college. COURSES OF INSTRUCTION All courses listed below are to be Riven in the Baker Laboratory of Chemistry. Those courses which are marked with the asterisk (*) may not be counted for upper- class group by candidates for the degree of Bachelor of Arts. INORGANIC CH EM ISTR Y *101. Introductory Inorganic Chemistry. Repeated in the second term. Credit three hours. Professor B rowne and Assistant Professor M cK in n e y . Lectures: M W F, n , T Th S, II. Baker, Main Lecture Room. Entrance credit in chemistry does not carry with it University credit in course 101 or 105. I f a student entering the University from a preparatory school desires credit in these courses he must pass an examination set by the Department of Chem­ istry. This examination is held in New York City and in Ithaca on the same day in September as the entrance examination. University credit in courses 101 and 105 that is obtained by passing this examination does not carry with it entrance credit in chemistry. Examinations for those ivho were unavoidably absent from the final examination in course 101 will be held at 2 p. m. on the day before instruction begins in the fall. *105. Introductory Inorganic Chemistry. Recitations and laboratory practice. Repeated in the second term. Credit three hours. Recitations, one hour a week, to be arranged. Laboratory sections: M F 2-4:30; T Th 2-4:30; W 2-4:30, S 8-10:30. Room 150. Professor B row ne, Assistant Professor M cK in n e y , and assistants. Chemistry 101 and 105 must be taken simultaneously unless permission has been obtained by the student from the Dean of his college and from the Depart­ ment of Chemistry to take either course alone. 130. Advanced Inorganic Chemistry. Throughout the year. Credit three hours a term. Prerequisite or parallel courses, Chemistry 405 and 410. Professor D en n is. M W F i i . Baker 107. Lectures. The chemical elements are discussed in the order in which they occur in the Periodic Table of Mendeleeff, with special attention to the group properties of the elements and to the relations of the groups to one another. The rare elements and the rare earths are treated in as great detail as are the more common elements. 135. Advanced Inorganic Chemistry. Either term. Credit one to six hours. Prerequisite, Chemistry 305 and 310. Professors D en n is and B row ne and assistants. Day and hour to be arranged. Baker 178 and 122. Laboratory practice. The preparation, purification, properties, and reactions of inorganic compounds including those of the rarer elements. Chemistry 135 is designed to accompany Chemistry 130, but either course may be taken separately. [140. Selected Topics in Advanced Inorganic Chemistry. Second term. Credit two hours. Prerequisite, or parallel courses, Chemistry 405 and 410. Professor B row ne. Not given in 1926-27.] 195. Research for Seniors. Throughout the year. Professors D enn is and B rowne and Assistant Professor M cK in n e y . See page 5. A N A LYTICA L CH EM ISTRY 205. Introductory Qualitative Analysis. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 101 and 105. Must be taken with Course 206. Assistant Professor N ichols, Dr. C o r e y , and assistants. DEPARTMENT OF CHEMISTRY 7 Lectures: Assistant Professor N ichols, M W F 9. Baker 107. Recitations: one hour a week, to be arranged. A study of the application of the theories of general chemistry to the systematic separation and detection of the common elements and acid radicals. Students in science are advised, and candidates for the degree of Bachelor of Chemistry are required, to take this course together with Course 206 instead of Course 210. 206. Introductory Qualitative Analysis. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 101 and 105. Must be taken with Course 205. Assistant Professor N ichols, Dr. C o r e y , and assistants. Laboratory section: M W F 2-4:30. Baker 50. Laboratory practice. A study of the properties and reactions of the common elements and acid radicals; the qualitative analysis of a number of solutions and solid compounds. Students in science are advised, and candidates for the degree of Bachelor of Chemistry are required, to take this course together with Course 205 instead of Course 210. *210. Introductory Qualitative Analysis. Shorter course. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 101 and 105. Dr. Corey and assistants. Lectures: Dr. C o r e y . T 12. Baker 207. Laboratory sections: T Th 8-10:30; T Th 2-4:30. Baker 50. The properties and reactions of the common elements and acids; their detec­ tion in various liquid and solid mixtures. 215. Advanced Qualitative Analysis. Second term. Credit one, two, or three hours. Prerequisite, Chemistry 220, 221, 305, and 310. Assistant Professor N ichols, Dr. C o r e y , and assistants. Day and hour to be arranged. Baker 50. Laboratory practice. Essentially a continuation of Course 206. The methods for separating and detecting a number of metals and acids not studied in Course 206, including many of the rare elements. The qualitative analysis of a number of solutions, solid mixtures, natural and commercial products will be required. For graduates and advanced undergraduates. 220. Introductory Quantitative Analysis. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 205 and 206. Must be taken with Course 221. Assistant Professor N ichols, Mr. T u cker , and assistants. Lectures: Assistant Professor N ichols. T Th 9. Baker 207. Recitations: one hour a week, to be arranged. A study of the fundamental principles of gravimetric and volumetric analysis with practice in stoichiometry. Students in science are advised, and candidates for the degree of Bachelor of Chemistry are required, to take this course together with Course 221 instead of Course 225. 221. Introductory Quantitative Analysis. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 205 and 206. Must be taken with Course 220. Assistant Professor N ichols, Mr. T u cke r , and assistants. Laboratory Sections: First term, M T W 2-4:30; T Th 10-12:30, S 8-1; second term, W Th F 2-4:30; T Th 10-12:30, S 8-1. Baker 252. Laboratory practice in the preparation and standardization of various volu­ metric solutions and the analysis of a variety of substances by volumetric and gravimetric methods. Students in science are advised, and candidates for the degree of Bachelor of Chemistry are required, to take this course together with Course 220 instead of Course 225. *225. Introductory Quantitative Analysis. Shorter course. Repeated in the second term. Credit three hours. Prerequisite or parallel course, Chemistry 210. Mr. T ucker and assistants. Lecture: Mr. T ucker. Th 12. Baker 207. Laboratory sections: T Th 8-10:30; T Th 9 -11 :3o; M W 2-4:30; T Th 2-4:30. Baker 252. A study of the fundamental principles of quantitative and vplumetric analysis. I O CORNELL UNIVERSITY Prerequisite, Chemistry 210 and 225 (205, 206, 220 and 221). Open to those who are taking course 220. Mr. Beach and assistants. Lectures and written reviews, Mr. Beach. M W P S 12. Baker, Main Lec­ ture Room. Laboratory section and oral reviews, M W 2-4:30. Baker 250. 395. Research for Seniors. Throughout the year. Professor Orndorff. See page 5. PH YSICAL CH EM ISTRY 405. Introductory Physical Chemistry. Throughout the year. Credit three hours a term. Prerequisite, Chemistry 305 (or 375) and Physics 5 and 31. Pro­ fessor Briggs. M W F 9. Baker 7. Lectures. A systematic presentation of modem chemical theory in which special attention is paid to the following topics: Gases, liquids, and solids; the theory of solution; reaction velocity, catalysis, and chemical equilibrium; the Phase Rule; colloid chemistry; thermochemistry; and elementary electrochem­ istry. Problems in physical chemistry. It is advisable, but not obligatory, that course 410 accompany this course. 410. Introductory Physical Chemistry. Throughout the year. Credit three hours a term. Prerequisite or parallel course, Chemistry 405. Professor Briggs and assistants. Laboratory sections: M T 2-4:30; S 8-1. Baker 1. Laboratory practice. Qualitative and quantitative experiments illustrating the principles of physical chemistry and including practice in performing physical chemical measurements. An important feature of this course is the presentation of detailed reports based upon data obtained in the laboratory. 415. Advanced Physical Chemistry. Throughout the year. Credit two hours a term. Prerequisite, Chemistry 405. Professor B ancroft. T Th 11. Baker 7. An exposition of the law of mass action in its application to chemical equilibrium and reaction velocities. 430. Applied Colloid Chemistry. Throughout the year. Credit two hours a term. Open to candidates for the degree of Bachelor of Chemistry if they have completed Chemistry 405, to others only by special permission. Professor B ancroft. T Th 10. Baker 7. Lectures. The theory of colloid chemistry and its application in the arts. 450. Applied Electrochemistry. Throughout the year. Credit two hours a term. Prerequisite, Chemistry 405. Professor Briggs. M W 12. Baker 7. Lectures. The theory of electrolysis and electromotive force; electrolytic ex­ traction and refining of metals; electrolytic manufacture of organic and inorganic compounds; theory and practice of storage cells; preparation of compounds in the electric furnace. Problems in electrochemistry. 455- Applied Electrochemistry. Throughout the year. Credit two hours a term. Prerequisite or parallel course, Chemistry 450. Professor Briggs and assistant. Day and hour to be arranged. Baker i-A. Laboratory practice. Qualitative and quantitative study of electrolysis; determination of electrical conductivity; potentiometric measurements; hydro­ gen ion concentration; determination of current and energy efficiencies in electro­ lytic and electrothermal work; electrolytic preparation of organic and inorganic compounds; tests of storage cells; preparation of compounds in the electric fur­ nace; measurement of furnace temperatures. [460. Theoretical Electrochemistry. Throughout the year. Credit two hours a term. Prerequisite, Chemistry 405. Professor B ancroft. T T h n . Baker 7. Lectures. The historical development of the subject with special reference to the theory of the voltaic cell. For advanced students in Chemistry or Physics. Not given in 1926-27.] 465. Advanced Physical Chemistry. Either term. Credit variable, but not to exceed six hours a term. Prerequisite, determined in each case by the professor in charge. Professors B ancroft and B riggs and assistants. Hour and work to be arranged. Baker 94. Laboratory practice. Students may elect in mass law, reaction velocity, or efficiency measurements with special reference to course 415; in photo-chemistry, DEPARTMENT OF CHEMISTRY II photography, or colloid chemistry with special reference to course 430; in con­ ductivity, or electrometric determinations with special reference to course 460; in electrolytic, or electric furnace products with special reference to course 450; in the application of physical chemical methods to organic chemistry. 495. Research for Seniors. Throughout the year. Professors Bancroft and Briggs. See page 5. OPTICAL CH EM ISTRY 505. Introductory Chemical Spectroscopy. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 210 and 225 (or 205, 206, 220 and 221). Open to those who have completed or are taking Physics 31. Assistant Professor Papish and assistants. Lectures and written reviews. Assistant Professor Parish. T Th 8. Baker 377. Laboratory sections: M W F 2-4:30. Baker 392 and 396. The construction and the use in chemical analysis of the spectroscope, polari- scope, refractometer, colorimeter, and nephelometer. The laboratory instruc­ tion is devoted to the training of the student in the use of these instruments in the solving of chemical problems. 510. Advanced Chemical Spectroscopy. Either term. Credit two or more hours. Prerequisite, Chemistry 505. Assistant Professor P apish and assistants. Day and hour to be arranged. Baker 396. Laboratory practice. The study of arc, spark, and absorption spectra and the application of spectroscopic methods to the identification of dyestuffs. Practice in one or more of the subjects mentioned may be selected by the student. 520. Spectrographic Methods. Either term. Credit one or more hours. Prerequisite, Chemistry 505. Assistant Professor P apish . Laboratory hours to be arranged. Baker 396. Conference, Th 12. Baker 377. Laboratory practice. The application of photographic methods to arc, spark, and absorption spectroscopy. Practice is also given in the application of ultra­ violet spectroscopy in chemical analysis. 525. Special Methods in Optical Chemistry. First term. Credit two hours. Prerequisite, Chemistry 505. Assistant Professor P apish . Lectures, Assistant Professor P apish . F 9. Baker 377. Laboratory, hours to be arranged. Baker 392. Lectures, demonstrations, and laboratory practice. Special optical instruments as applied to the solution of problems arising in the chemical industries and in research; modifications of commonly employed polarimeters, refractometers, nephelometers, colorimeters, etc., as employed in specific industries. 530. Introductory Chemical Microscopy. Repeated in the second term. Credit three hours. Prerequisite, Chemistry 210 and 225 (or 205, 206, 220 and 221) and Physics 31, or special permission. Professor Chamot, Dr. Mason, and assistants. Lecture: Professor Chamot. First term, M 12; second term, M 10. Baker 377. Laboratory sections: M T 2-4:30; T Th 10-12:30; Th F 2-4:30. Baker 378. Lectures and laboratory practice. The use of the microscope and its acces­ sories ; microscopic methods as applied to chemical and other scientific investiga­ tions; micrometry; the examination of crystalline compounds and industrial materials; recognition of textile and paper fibers, etc. The application of micro­ scopic methods to quantitative analysis. 535. Advanced Chemical Microscopy. Repeated in the second term. Credit three or more hours. Prerequisite, Chemistry 530. Professor C hamot, Dr. Mason, and assistants. Laboratory periods: M T Th F 2-5, T Th 9-1. Baker 378. Conference, T 12. Baker 377. Laboratory practice in the examination and analysis of inorganic substances containing the more common elements with special reference to rapid qualitative methods and to the analysis of minute amounts of material. 540. Advanced Chemical Microscopy. Second term. Credit two hours. Prerequisite, Chemistry 530. Professor Chamot, Dr. M ason, and assistants. Day and hour to be arranged. Baker 378. Laboratory practice. Organic qualitative microscopic analysis as applied to the detection of common commercial organic compounds, vegetable alkaloids, 12 CORNELL UNIVERSITY “strong drugs,” etc., with particular emphasis upon the analysis of minute quan­ tities of material. In this course work may be elected in the microscopy of textile or paper fibers. 542. Special Methods in Chemical Microscopy. Second term. Credit two hours. Prerequisite, Chemistry 530. Professor C hamot and Dr. M ason . W F 9. Baker 377. Lectures and demonstrations. A discussion of microscopic methods as applied to the solution of industrial and research problems. Microscopes of special and unusual construction, such as ultramicroscopes, supermicroscopes, luminescence microscopes, long distance microscopes, etc.; their uses and their limitations. 545. Microscopy of Commercial Alloys. Second term. Credit two hours. Prerequisite, Chemistry 530, or special permission. Professor C hamot, Dr. M ason and assistants. Th F 2-4:30. Baker 384. Laboratory practice. An introduction to the methods employed in the micro­ scopic examination of metals, alloys, and other metallurgical products; practice in grinding, polishing, and etching specimens for microscopic study; metallo- graphic microscopes and their use. This course may be extended to include other materials of construction. [550. Microscopy of Foods and Beverages. First term. Credit two hours. Prerequisite, Chemistry 530. Professor C hamot, Dr. M ason , and assistants. Laboratory hours to be arranged. Baker 378. Conference, Th 12. Baker 377. Laboratory practice. The application of microscopic methods to the examina­ tion of foods and beverages for the purpose of ascertaining their purity and for the detection of deteriorations, adulterations, and admixtures. Not given in 1926-27.] [555- Introductory Photomicrography. Second term. Credit two or more hours. Prerequisite, Chemistry 530. Professor C hamot and Dr. M ason . Day and hour to be arranged. Baker 382. Laboratory practice. Not given in 1926-27.] 595. Research for Seniors. Throughout the year. Professor C hamot, Assistant Professor P apish , and Dr. M ason . See page 5. SAN ITA R Y CH EM ISTRY 605. Introductory Sanitary Chemistry (Foods). First term. Credit two hours. Prerequisite, Chemistry 305 (or 210, 225 and 375). Dr. G eo rgia . T Th II. Baker 377. Lectures. Chemistry of foods, beverages, and food accessories; special ap­ paratus; adulteration and misbranding, sweeteners, preservatives, food colors, food poisonings, and methods for their detection. Relation of the chemical composition of materials used in the household to the public health. Garbage disposal. It is advisable, but not obligatory, that Course 610 accompany this course. 610. Introductory Sanitary Chemistry (Foods). First term. Credit two hours. Prerequisite or parallel course, Chemistry 605. Dr. G eorgia and assist­ ant. Laboratory sections at hours to be arranged. Baker 352. Laboratory practice. Laboratory exercises designed to illustrate the material gresented in course 605. General and special methods of analysis of foods, everages, and food accessories with special reference to the detection of adultera­ tion. The use of saccharimeters, refractometers, cryoscopes, muffle furnaces, vacuum ovens, etc. 615. Introductory Sanitary Chemistry (Water). Second term. Credit two hours. Prerequisite, Chemistry 305 (or 210, 225 and 375). Dr. G eo rgia . T Th 11. Baker 377. Lectures. Pollution of water; physical, chemical, bacteriological, and micro­ scopical examination of water for household and municipal purposes; examina­ tion of sewage and sewage effluents; introduction to the methods of water purifica­ tion, water softening, and sewage disposal, and their control. Interpretation of analytical results and the preparation of sanitary surveys. It is advisable, but not obligatory, that Course 620 accompany this course. DEPARTMENT OF CHEMISTRY 15 Lectures. The relation of chemistry to agriculture, and an introduction to the study of the composition and chemical properties of plants, fertilizers, feed stuffs, insecticides, and fungicides. *880. Elementary Chemistry of Food Products. Second term. Credit two hours. Prerequisite, Chemistry 101. Professor C avanaugh. W F 10. Baker 377. Candidates for the degree of Bachelor of Chemistry may not receive credit for this course toward the degree. Lectures. The chemical composition, physical and physiological properties, sources, and methods of manufacture of the principal food products. 895. Research for Seniors. Throughout the year. Professor C avanaugh. See page 5. Seminary 905. Seminary. Credit one hour. M 5. Baker 107. For seniors who are candidates for the degree of Bachelor of Chemistry. Non-Resident Lectureship in Chemistry 1000. Selected Topics in Inorganic Chemistry. First term. Credit two hours. Seniors in the course in Chemistry may elect these lectures, and juniors may do so on special permission. Professor Fritz Paneth, University of Berlin. T Th 4:30. Baker 107. CORNELL UNIVERSITY OFFICIAL PUBLICATION Entered as second-class matter, December 14, 1916, at the post office at Ithaca, New York, under the Act of August 24, 1912. Issued at Ithaca, New York, twice a month from December to June inclusive, and monthly from July to November inclusive. This series of pamphlets is designed to give prospective students and other persons information about Cornell University. No charge is made for the pam­ phlet unless a price is indicated after its name in the list below. Requests for pamphlets should be addressed to the Secretary of the University at Ithaca. Money orders should be made payable to Cornell University. 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