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Nikhila Mahadevapuram <nmahadevapuram2@uh.edu>
Monday, October 14, 2013 1:51 PM
H_20133_ENGI_2334_11716 (2013FA-11716-ENGI2334-Introduction To
Thermodynamics) :
H_20133_ENGI_2334_11716 (2013FA-11716-ENGI2334-Introduction To
Thermodynamics): EXAM 1 - Grade
Exam1L.pdf
Grades for Exam 1 are uploaded on Black board.
Class average i have attached the histogram for the class performance.
Best
Nikki
No. of Students
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CHEE 2334: Introduction to Thermodynamics
Fall 2013, Exam 1
Name (Print) | Ucvoe People soft # womyyyiiiity_
Exam Format: 4 problems, 80 pts total.
Extra credit: 1 problem, 10 pts total
No cell phones.
Do NOT write on the back of the page. Extra paper is included in the packet.
Show all work to receive full or partial credit.
Clearly explain any assumptions/approximations.
Put a box around your final answer (for calculations).
Include units where appropriate.
Your work must be legible! !!!
Return the formula sheet along with exam booklet with name and people
soft #
IT vemos vec) blank
ges
Nz o
» At
Problem 2: 20 pts. no AT )
An ideal gas goes through an expansion process in\hich the volume triples. Which
process will lead to the larger work output: An isothermal process or a polytropic process
with n= 1.77
What percentage more work is done by that process? C-=PA
Stare 4 [ State om Sw = Fely
p - Ow = Phady
| fae Sw * Pay
VY zy Vy -2y
WwW, = 5” pay
/
Problem 3: 20 pts.
A nozzle receives an ideal gas flow with a velocity of 50 mis fen exit is at 100 kPa,
400 K with a velocity of 350 m/s, Determine the inlet temperature if the gas is argon,
eth
hydrogen or oxygen. State all assumptions.
Soe Ste phenol.
~ Ve ss0"s ex wena
Vv, 250 "s * No AQ “4
(a | T= 4ookk aiuae
y _: ne
@ _ <reh Crete og os
oo re too ———
| Ar iv 8 25207, = ~ 59 (ua) *oQexe? /
\ d Teno |
US; 7BL )
go
2 Hea 400) # cose |
ooo
|
= 4622.4 }
| ee —
os 27, 2 TAR (Ge) + 68. LO
\ Oryge™ e127, > +l — |
\ i
\ 12 6S 4IS K |
\ I 7 hl?
\ 6 a J
Problem 4: 20 pts.
Find the missing property: v = specific volume (m’/kg), P = Pressure, u = specific
intemal energy.
a) NH; at 30°C, v=0.1 m’/kg, P =?, u=?
, -b) HyO at 175°C, v=2, P=?, w= 2100 ki/kg Hy) — fa Dore phase
f c) H2O at 200 kPa, 150°C, v2, u=?
“* | y= Ws" < 7
Nig — Dn Rome -2 phase | i
aoe, | Wz 2IOO Key
Te Cc | —
v2 | Mis | vee
| a ak
(Pa neT er.) [CR S92 Ae) Se
as (2307 Kya ju
‘Aus = WatX Ue
Vag? VE * VS | acs = THOM, + xX 1342.08
Ava,
ol nF[ks * 00180 + X(1OBS) )
Quality X= IO4% SY
/ _ksj,|
wz (Baowe J) + JOU (10164 ies)
2, coil | CRI 2/588 )
= 7 RF |
[Xero Peg | | fri =teor=)
© HO ~ ae heateoh 7
P= oc kee
© APPENDIX A Si UNITS: SINGLE-STATE PROPERTIES -++---++
TABLE AS
Properties of Various Ideal Gases at 25°C, 100 kPa* (SI Units)
Chemical Molecular R p Ce Cv é
Gas Formula Mass (ke/kmol) = (kJ/kg-K) (kg/m?) (K/cg-K) ——(kuJ/kg-K) ke =
Steam H,0 18.015 0.4615 0.0231 1.872 1.410 1.327
Acetylene CiHy 26.038 0.3193 10s 1.699 1,380 1231
Air _ 28.97 0.287 1.169 1,004 0.717 1.400
Ammonia NHy 17.031 0.4882 0.694 2.130 1,642 1.297
Argon Ar 39.948 0.2081 1.613 0.520 (Ou2) 1,667
Butane ~ CaHio 58.124 0.1430 2.407 L716 1.573 1.091
| Carbon dioxide CO; 4401 0.1889 1.775 0.842 0.653 1.289
Carbon monoxide CO 28.01 0.2968 113 1.041 0.744 1.399
Ethane CrHy 30.07 0.2765 1.222 1.766 1.490 1.186
Ethanol C.H;OH 46.069 0.180S 1.883 1.427 1.246 1.145 |
Ethylene CaHy 28.054 0.2964 113d 1.548 1.252 1.237
Heliura He 4.003 2.0771 0.1618 5.193 3.16 1.667 1
Hydrogen Hy 2.016 4.1243 0.0813 14.209 0.085 1.409 |
Methane CHa 16.043 0.5183 0.648 2254736 1.299
Methanol CHjOH 32042 0.2595 131 1.405 1.146 1.227
Neon f Ne » > 20.183 0.4120 0.814 1.03 0.618 1.667
Nitric oxide NO 30.006 02771 1.21 0.993 0,716 1.3877
Nitrogen Na 28.013 0.2968 113 1.042 0.745 1.400
Nitrous oxide N20 44013 0.1889 1.775 0.879 1.274
n-Octane CH 114,23 0.07279 0.092 wu 1.044
Oxygen Q, 31.999 0.2598 1.292 0.922 662 1.393
Propane Cie 44.094 0.1886, 1.808 1.679 1.490 1.126
R-12 CChr; 120.914 0.06876 4.98 0.616 0.547 ~ 1.126
R-22 CHCIF; 36.469 0.09616 3.54 0.658 0.562 LA71
R-32 CF2H) 52.024 0.1598 2.125 0.822 0.662 1.242
R-125 CHF,CF,; — 120.022 0.06927 4.918 0.791 0.722 1.097
R-13da CF;CH;F — 102.03 0.08149 4.20 0.852 0.771 1.106
| R-410a - . 72.585 0.11455 2.967 0.809 0.694 1.165
Sulfur dioxide SO, 64.059 0.1298 2.618 0.624 0.494 1.263
Sulfur trioxide 80; 80.053 0.10386 3.272 0.635 0.531 1.196
“Or saturation pressure if itis less than 100 kPa.
i
:
BE
pe
sete “APPENDIX D EQUATIONS OF one soeteenee
T
SIMPLE FLUID
Zc = 0.2901
Compressibility factor, Z
0.01 Ou 1 10
Reduced pressure, P,
FIGURE D.1 Lee~Kesler simple fluid compressibility factor.
pts APPENDIX D EQUATIONS OF STATE «++
TASLE D.2
The Lee-Kesler Equation of State
The Lee-Kesler generalized equation of state is
ah
Dad+2
in which
Leaks
ain
The set of constants is as follows:
Constant Simple Flulds Cansrant Simple Fluids
by 0.118 1193 C3 0.0
by 0.265 728 cy 0.042 724
by 0.154 790 dy x 10* 0.155 488
ba 0,030 323 dy x 10 0,623 689
ef 0.023 6744 B 0.653 92
o 0.018 6984 y 0.060 167
TABLE D.3
Saturated Liquid~Fapor Compressibilities, Lee~Kesler Simple Fluid
Tr 0.40 0.50 0.60 0.70 0.30, 0.85 0.90 0.95 1
P, sat 2.764 4.6E-3 0.028 0.099 0.252 0.373 0.532 0.737 1
Z 6.5E-5 9.SE-4 0.0052 0.017 0,042. 0.062 0.090 9132 0.29
Z, 0,999 0.988 0.987 0.897 0.807. 0.747 0.673 0.569 0.29
TABLE D.4
Acentrie Factor far Some Substances
Substance w Substance w
Ammonia NH; 0.25 Water H:0 0.344
Argon Ar 0.001 a-Butane CyHia 0.199
Bromine Bry 0.108 Ethane Cie 0.099
Helium He —0.365 Methane CHy 0.011
Neon Ne ~0.029 R-32 CF Ha 0.277
Nitrogen Na 0.039 | R-125 CHF2CFs 0.305
TABLE B.1.3
Superheated Vapor Water
. @ APPENDIX B SIUNITS: THERMODYNAMIC TABLES **t+1sese-s-ressesereseee
Temp. v a A s v 4 A s
co (m'/kg) (kJ/kg) (kJ/kg) (kJ /kg-K) (m/kg) (kJ/kg) (k/kg) (kJ/kg-K)
P = 10 kPa (45.81°C) P= 50 kPa (81.33°C)
Sat. 1467355 2437.89 (2584.63 8.1501 3.24034 2483.85 2645.87 7.5939
30 1486920 2443.87 2592.56 8.1749 - - — -
100 1719561 2515.50 2687.46 8.4479 3.41833 2511.61 2682.52 7.6947
150 1951251 2587.86 =—-2782.99- 8.6881 3.88937 2585.61. 2780.08 7.9400
200 21.82507 2661.27 2879.52 8.9037 4.35895 2659.85° 2877.64 8.1579
250 2413559 2735.95 2977.31 9.1002 4.82045 2734.97 2975.99 8.3555
300 2644808 2812.06 3076.51 9.2812 5.28391 2811.33 3075.52 8.5372
400 3106252 2968.89 = 3279.51 9.6076 6.20929 2968.43. «3278.89 8.8641
500 39.67896 © 3132.26 © 3489.05 9.3977 7.13364 3131.94 3488.62 9.1845
600 4029488 © 3302.45 «370540 ~——10,1608 8.05748 3302.22 3705.10 9.477
700 4491052 3479.63 «3928.73 10.4028 8.98104 3479.45 «3928.51, 9.6599.
800 4952599 3663.84 «4159.10 10,6281 9.90444 3663.70 4158.92 9.8852
900 5414137 3855.03 4396.44 10.8395 10.82773 385491 = 4396.30 10.0967
1000 58.75669 4053.01 4640.58 «11.0392 11.75097 4052.91 4640.46 10.2964
1100 6337198 4257.47 4891.19 11.2287 (2.67418 425737 4891.08 10.4858
1200 6798724 4467.91. 5147.78 11,4090 13.59737 4467.82 5147.69. 10,6662
1300 72.60250 4683.68 += 5409.70 14.5810. 1452054 4683.58 5409.61 10,8382
100 kPa (99,62°C) 200 kPa (120.23°C)
Sat. 1.69400 2506.06 2675.46 7.3593 0.88573 2529.49 2706.63 7.1271
150 1.93636 2582.75 2776.38 72.6133 0.95964 23 S3_2768.80 1.2195
200‘ (217226 = 2658.05 2875.27 7.8342 1.08034 2870.46 7.5066
250 2.40606 = «2733.73. 2974.33. «8.0332. i9e8o © 2731.22 ° 7.1085"
300 2.63876 = 2810.41. «3074.28 = 8.2157 1.31616 2808.55 3071.79 7.8926
400 3.10263 2967.85 3278.11 8.5434 1.54930 2966.69 -3276.55 8.2217
$00 3.56547. 3131.54 = 3488.09 8.8341 1.78139 3130.75 -3487.03 8.5132
600 4.02781 3301.94 3704.72 9.0975 2.01297 3301.36 = 3703.96 8.7769
700 4.48986 = 3479.24 «3928.23 9.3398 2.24426 © 3478.81 3927.66 9.0194
300 495174 3663.53 4158.71 9.5652 2.47539. 3663.19 4158.27 9.2450
900 5.41353 3884.77 4396.12 9.7767 2.70643 3854.49 4395.77 9.4565
1000 5.87526 4052.78 4640.31 9.9764 2.93740 4052.53 4640.01 9.6563
1100 6.33696 4257.25 4890.95 10.1658 3.16834 4257.01 4890.68 9.8458
1200 6.79863 4467.70 «5147.56 10.3462 3.39927 4467.46 © 5147.32 10.0262
1300 7.26030 4683.47 © 5409.49 10,5182 3.63018 4683.23 5409.26 10.1982
300 kPa (133.55°C) 400 kPa (143.63°C)
Sat. 0.60582 © -2543.55 2725.30 6.9918 0.46246 = «-2593.55 2738.53 6.8958
150 0.63388 «=—-2570.79 2760.95 1.0778 0.47084 «2564.48 «(2752.82 6.9299
200 0.71629 2650.65 (2865.54 73115 0.53422 2646.83 2860.51 7.1706
Bree B_ SIUNITS: THERMODYNAMIC TABLES «++
TABLE B.1.5,
Saturated Solid-Saturated Vapor, Water
1.010878:
0.010874
—22 0.08535 0.0010871 1357.863
—24 0.07012 0.0010868 1639,752
-26 0.05741 0.0010864 1986775
d.001086r
68353 2414,200%
d.0010858 '
Specific Volume, m'/kg Internal Energy, ki/kg
Temp. Press. Sat. Solid Evap. Sat. Vapor Sat. Solid Evap. Sat. Vapor
eo (kPa) ” Vg Ye uy Mig My
0.01 0.6113 0.010908 206.152 206.153 —333.40 2708.7 2375.3
0 0.6108 0.0010908 206.314 206.315 333.42 2708.7 2375.3
-2 0.5177 0.010905 241.662 241,663 -337.61 2710.2 2372.5
4 0.4376 0.010908 ©." 283.798." 283.799- 2 < 341.78" 27S 2369.8
-6 0.3689 | o.0o10g98, |; 334138. 334139 34s 1 279 23670
“ ,0,0010894 "394.413. 394.414 —356.02° 2714.2 2364.2
0.0010891 466.756 466,757 —354.09 2715.5 2361.4
0.010888 553,802 593.803 — 358.14 2716.8 2358.7
0.0010884 658,824 658.824 —362.16 2718.0 2355.9
ieites iS oot ;
940,183,
1128.13
1357.864
1639,753
1986.776
* 0.00108S4" ©." 3601.82" gq. 2330.8"
0.0010851 4416.252 4416253 2728.7 2328.0
0.02016 0.0010848 5430.115 5430.116 2729.6 2325.2
—38 0.01618 0.0010844 6707.021 6707.022 2730.5 2322.4
W407 0.01286" 0.010841" 8366.398: °', 9366.396 °° QB 196
2719.2!
2721.
2722.7
2724.7 2342.0
2724.8 2339.2
2 272. Fe
oT
. ® APPENDIX B Si UNITS: THERMODYNAMIC TABLES
TABLE B.2
Thermtadynamic Properties of Ammonia
TABLE 8.2.1
Saturated Ammonia
Specific Volume, m'/kg Internal Energy, kJ/kg
Temp. Press. Sat. Liquid Evap. Sat. Vapor Sat. Liquid Evap. Sat. Vapor
(«Cy (kPa) vy Yy¢p My uy an ay
~50 40.9 0.001424 2.62557 2.62700 —43.82 1309.1 1265.2
~45 54.5 0.001437 2.00489 2.00632 ~22.01 1293.5 1271.4
—40 77 0.001450 15511 1.55256 0.10 1277.6 1277.4
-35 93.2 0.001463 1.21466 1.21613 21.93 1261.3 1283.3
-30 119.5 0.001476 0,96192 0.96339 44,08 1244.8 1288.9
-25 151.6 0,001490 0.76970 0.77119 66,36 1227.9 1294.3
~20 190.2 0.001504 0.62184 0.62334 88,76 1210.7 1299.5
-15 236.3 0.001519 0.50686 0.50838 111.30 1193.2 1304.5
—10 290.9 0.001534 0.41655 0.41808 133.96 1175.2 1309.2
-5 354.9 0.001550 0.34493, 0.34648 156.76 1157.0 1313.7
0 429.6 0.001566 0.28763 0.28920 179.69 1138.3 1318.0
5 515.9 0.001583 0.24140 0.24299 202.77 1119.2 1322.0
10 615.2 0.001600 0.20381 0.20541 225.99 1099.7 1325.7
15 728.6 0.001619 0.17300 0.17462 249.36 1079.7 1329.1
20 857.5 0.001638 0.14758 0.14922 272.89 1059.3 1332.2
25 1003.2 0.001658 0.12647 0.12813 296.59 1038.4 1335.0
30 1167.0 0.001680 0.10881 0.11049 320.46 _ 1016.9 1337.4
38 1350.4 0.001702 0.09397 0.09567 144,50 994.9 1339.4
40 1584.9 0.001725 0.08141 0.08313 368.74 972.2 1341.0
45 1782.0 0.001750 0.07073 0.07248 393.19 948.9 1342.1
50 2033.1 0.001777 0.06159 0.06337 417.87 924.8 1342.7
55 2310.1 0.001804 0.05375 0.05555 441.79 399.9 1342.7
60 26144 . 0.001834 0.04697 0.04880 467.99 874.2 1342.1
65 2947.8 0.001866 0.04109 0.04296 493.51 847.4 1340.9
70 3312.0 0.001900 0.03597 0.03787 519.39 819.5 1338.9
75 3709.0 0.001937 0.03148 0.03341 $45.70 790.4 1336.1
80 4140.5 0.001978 0.02753, 0.02951 $72.50 759.9 1332.4
85 4608.6 0.002022 0.02404 0.02606 599.90 7278 1327.7
90 5115.3 0.002071 0.02093 0.02300 627,99 693.7 1321.7
95 5662.9 0.002126 0.01815 0.02028 656.95 657.4 1314.4
100 6253.7 0.002188 0.01565 0.01784 686.96 618.4 1305.3
| 10s 6890.4 0.002261 0.01337 0.01564 718.30 375.9 1294.2
110 1878.7 0.002347 0.01128 0.01363 751.37 529.1 1280.5
115 8313.3 0.002452 0.00933 0.01178 786.82 476.2 1263.1
120 9107.2 0.002589 0.00744 0.01003 825.77 414.5 1240.3
125 9963.5 0.002783 0.00554 0.00833 870.69 337.7 1208.4
130 10891.6 0.003122 0.00337 0.00649 929.29 226.9 1156.2
132.3 1333.2 0.004255 0 0.00426 1037.62 0 1037.6