Final Exam Review for Organic Chemistry I Honors | CHEM 547, Study notes of Organic Chemistry

Download Final Exam Review for Organic Chemistry I Honors | CHEM 547 and more Study notes Organic Chemistry in PDF only on Docsity! Chemistry 547 Preparing for the Final Exam The final exam will be comprehensive. It is most effective to review class notes, previous quizzes and examinations and homework problems. This review sheet is NOT comprehensive. Final Examination Friday 12/17 8 - 10 am Important Reaction Mechanisms to Review cyclopentadiene + base p462 benzylic resonance p 444 Diels-Alder orbitals p 417, mechanism 410 - 415 HX + dienes p 407 allylic resonance p 397 allylic SN1 p 393 alkyne hydration and tautomerization p 375 - 376 alkyne acidity p 365 substitution vs. elimination 344- 345 tosylate chemistry p347 - 349 SN1 with rearrangement p 340 stereochemistry 296, 305 free radical chain polymerization p 264 alkene ozonolysis 259- 260 HBr + peroxides + alkenes p 254 Br2 + alkenes 252 halohydrin formation 253 hydroboration BH3 addition 248 alkene hydration 241 alkene + HX 233 E1 mechanism 215 E2 mechanism 211 - 214 alcohol dehydration 203 alkane free radical halogenation 168 alcohol + HBr 149 and 159 Two-step Synthetic problems CN O OH Br H D H D KOt-Bu acetylene O H H Show how these substances can be made by Diels-Alder reactions Show the major product OH O O H H N3 CO2H Cl 1-pentyne OH toluene OCH3 Nomenclature (with stereochemistry!) Br H H Br OH Br CH3 H Br CH3 H HO H H CH3 CH HH3C CH3 Draw the most stable conformation. Draw an energy diagram for the MO's of 1,3,5-hexatriene. Show orbital occupation. Label HOMO and LUMO. Draw each orbital complete with phase. Now you deserve a nap! CH3 H