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Understanding Van der Waals Forces and Colloidal Particles: Interactions and Stability, Exercises of Geology

The concepts of van der waals forces and colloidal particles, discussing their interactions, electrostatic stabilization, and significance in determining intermolecular distances and energies. It covers topics such as hamaker constants, london dispersion forces, and hard sphere interactions.

Typology: Exercises

2012/2013

Uploaded on 04/19/2013

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Download Understanding Van der Waals Forces and Colloidal Particles: Interactions and Stability and more Exercises Geology in PDF only on Docsity! L 27.1. Ans: 27.2. Ans: 27.3. Ans: 27.4. 27.5. Ans: ecture-27 What is Ha The Hamake where a and C is the The Hamak from the Va What are d Colloidal p similar par electrical ch tend to scre that while hindrance i What is har Hard spher fluids and spheres tha atoms and approximat is non zero of electroni How can Ef We have see A12 can be w A12 = – 12 π Now the ind Contact Ang Further, by c A11 = 24πd02 Further one Thus, we obs What is th curve? It signifies t molecules i. -30 Inter maker’s con r constant A nd are t coefficien er constan n der Waa ifferent type articles can ticle tend arge or (p en this attr Coulombic s responsib d spehere a es are wide solids. In t cannot ov spherical ion sugges , even whe c orbital. fective Ham n that when ritten as: d02 (γ12LW – ividual LW le Goniome onsidering γ1LW can also get erve that A12 c e physical hat at that p e they physic molecular stant? Wha can be defi he number t in the part t provides ls pair poten s of Colloid either Ele to attach t olymer mol action, form repulsion i le for steric pproximati ly used as m this theory erlap in spa molecules ts that the n they are a aker Const two blocks γ1LW – γ2LW) components try. Thus, if 1 and 2 are o A12 = √ (A11 an be express significance oint, the se ally come in Forces b t is its signi ned for a Va of atoms p icle-particl the means tial, al Stability ctrostatical o each oth ecules) atta ing a stabl s responsib stabilizatio on? odel partic the atoms ce. They m experience separation d t contact, d ant be mea of material of surface d0 is known f the same m . A12) ed in terms o of the low paration dist to contact. B etween Pa ficance? n der Waals er unit volu e pair intera to determin ? ly stabilize er in vacu ched to the e dispersion le for elec n. les in the s are simply imic the e at very c istance bet ue to stiff sured? s 1 and 2 co and interfac , then A12 ca aterial, γ11L f physically m est point in ance is min eyond this, rticles an (vdW) body me in two ction. e the intera . d or Steric um or air surface of . We may trostatic sta tatistical m considere xtremely st lose dista ween two a born repuls me in conta ial tension c n be determi W = 0, and th easurable qu the Leon imum for ei a repulsive d Surface -body intera interacting ction para ally stabili . The pres colloidal p further wan bilization, echanical th d as impe rong repuls nces. Hard toms or m ion due to ct in air or an be determ ned. erefore antities. ard-Jones p ther two su regime begin s ction: bodies meter C zed. All ence of articles t to add entropy eory of netrable ion that sphere olecules overlap vacuum, ined by otential rfaces or s. Docsity.com
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