Lecture Slides on Pesticides Labels - Weed Science | CS 414, Study notes of Agricultural engineering

Download Lecture Slides on Pesticides Labels - Weed Science | CS 414 and more Study notes Agricultural engineering in PDF only on Docsity! Pesticide Labels CS 414 What is a label? • A label is the information printed on or attached to the pesticide container © Labels MSDS Home Page - Windows Internet Explorer 686- Gite: .cdms,netLabelsMsds/l MDefault.aspx Fl [S|[x Google ||G\+ ¥ ico 3 SM EF + Gy Bookmarks~ | Eh popups okay Check » “4 Autolink File Edit View Favorites Tools Help [mh Send tow ae abels MSDS Home Page Search for: : coms | 2 All Reference Books CDMS’ Agro-chemical database is the most widely used and trusted resource for critical agronomic, regulatory, and use criteria. DOG |serek —country:[41 Labels / MSDS @all Segments © Crop OTRO Srand Name: All Supporting Agro- Chemical Manufacturers Manufacturers Other Search Options Terms of Use (alte ses iu eens ss cece So ) |) ttn: /fpremier,cdms.net/nebapls/formsloginRef.asp? /ebapis ! 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Done Tene Seen a ee usec [Eiht jue.cams net LabelsMsdsfLMDeFaut.aspx ¥] |#4]| 2] [cooole Google |(G~pestiide labels) 60> I SM Gi~ | ey wockmarts~ [Er romups okey || “YF check + \ autatink + cuts [esendto~ [El pesticide (El abet Qsetings~ File Edt View Favorites Tools Help ue [hte MSDS Home Page i (Bp ~ [ip eage - Took ~ CDMS’ Agro-chemical database is the most Pete ee Rate eles ret omar ECM Scat oo! a ee ee ae Labels / MSDS Search Results for Osprey Manufacturers Product Manufacturer Category Labels MSDS Bayer Agriculture/Crap Protection Labels & MSDS - CropScience USA a & Other Search Options Osprey™ Terms of Use Serer nn ee es | Rioo% - Tene Seen a ee usec Bibrtto: mw.coms net /LabelsMscls/LMDeFault spx?pd=72318t—= ¥] |#4]| 2] [cooole Google |(G~pestiide labels) 60> I SM Gi~ | ey wockmarts~ [Er romups okey || “YF check + \ autatink + cuts [esendto~ [El pesticide (El abet Qsetings~ File Edt View Favorites Tools Help ue [hte MSDS Home Page i (Bp ~ [ip eage - Took ~ CDMS’ Agro-chemical database is the most Pete ee Rate eles ret omar ECM Scat oo! a ee ee ae Labels / MSDS Bayer CropScience Osprey™, EPA Reg No. 264-802 Manufacturers Available PDF files for Viewing: a ars 2 specimen Label , Ca 03/31/04 © specimen Label , EPA 9/19/05 Terms of Use 4 24(c) Registration , WA-060010 For Control of Italian Ryegrass and Wild Oats in Fall-Sown or Winter Triticale AS 24(c) Registration , CA-070001 For Cantrol of Italian Ryegrass and Wild Oats in Fall-Sovn or Winter Triticale Ae msps , 12/21/2007 Version 2.0 Een eer ee es | Rioo% - Peni aT LUD Ue OO eA ai eae se )> tf coms. nt /LDat/ 14624005 vl Google Go http f/vv.ccms net Dat de dF 4K t oogle 00D SM Be wy boclmaris |Erropups okay] “check - \ sutoins ~ Ve jpuroril [Mp sendtor ) (pesticide (Bl labet (OD settings~ File Edt GoTo Favorites Help ~ [page - Ge took « ke [Bre ayo cds. net /L Dat 46]H005 dF lal elem) | a ie ) Bayer CropScience OSPREY™ Herbicide ‘A Herbicide for the Control of Annual Grass and Broadleaf Weeds in Fall- sown or Winter Wheat ‘ACTIVE INGREDIENT: Mesosulfuroretvethy!” (CAS No. 208465.21-8) 45% INERT INGREDIENTS: 955% Protected by U.S. PatentNo. 5.648.315 and 6,688,745 TOTAL: 100.0% “This product is a water dispersible granule containing 4.5% of active ingredient, Mesosulfuron-Mthy/, by weight, EPA. Reg. No, 264-802 E.P.A. Est. No.65387-AR-001 KEEP OUT OF REACH OF CHILDREN CAUTION Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (W you do not understand the label, find someone to explain it to you in detail) For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577 For PRODUGT USE Information Gall 1-866-99BAYER (1-866-992-2937) FIRST AID IF IN EYES: + Hold eye open and rinse skawty and gently with water for 15-20 minutes. + Remove contact lenses, if present, afterthe frst S minutes, then continue rinsing + _ Gall poison control center or doctor for treatment advice. IFSWALLOWED: — | + Immediately calla poison contol center or doctor for treatment advios, + Do nat induce vomiting unless told ta do so by a poison contol center or doctor. + Have person sip a glass of watorif able to swallow. + Do not give anything by mouth to an unconscious or esnvusing perscn, IF ONSKIN OR ‘+ Take off contaminated dothing. ‘CLOTHING: + Rinse skin immedistaly with planty of water for 15-20 rninutes + Goll a poison control center or doctor for tesiment advice, PRECAUTIONARY STATEMENTS. CAUTION HAZARD TO HUMANS AND DOMESTIC ANIMALS, Harel if swalloned or absorbed through skin. Causes moderate «ys irlation. Avoid contact with skin, eye or clothing. Wear protective eyewear (safety glasses. PERSONAL PROTECTIVE EQUIPMENT (PPE) Some materials that ae chemica-ecistantto ths product aretisted below. Ifyou want more option, follow theindrucons fr category ‘AonanEPA chemical mistanoe category selection chart Applicators and other handlars must weer: Leng-dlesved chit and long pants, cocks, chose, chemical reictant lovee auch ae barr laminate, butyl rubber > {4 mi, nile rubber > 14 ni, or neoprene rubber > 14 mis, and protective eyewear (softy glasses Follow manufladure's instructions for cleaningiainiaining PPE. If no such instutions for washable, use detergent and hot water. Koop and wash PPE separaaly from otherlaundty | @ unkrown zone Pesticide Labels and Labeling • Pesticide labeling gives users instructions on how to use the product safely and correctly • Pesticide users are required by law to comply with all the instructions and directions for use in pesticide labeling From page 2 from Osprey label ENGINEERING CONTROL STATEMENT When handlers use closed systems, enclosed cabs or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should: = Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. = Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. = Remove Personal Protective Equipment immediately after handling this product. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate any body of water and do not apply when/where conditions could favor runoff. Do not contaminate water by cleaning of equipment or disposal of equi DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Do not use this product until you have read the entire label. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted entry intervals. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 4 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated such as plants, soil or water, is coveralls, socks, shoes, chemical resistant gloves such as barrier laminate, butyl rubber > 14 mils, nitrile rubber > 14 mils, or neoprene rubber > 14 mils, and protective eye wear. The Label is the Law! It is a binding, legal agreement between: • US EPA • Product registrant(s) • Product user Summary of Data Requirements for Registration • Product chemistry (6 tests) - Active ingredients - Description of raw materials and manufacturing process • Physical and chemical characteristics (21 tests) - Melting/boiling points, pH, solubility, etc. - Flammability, corrosion, reactivity, etc. - Storage stability Summary of Data Requirements for Registration (continued) • Wildlife and aquatic organisms (22 tests) - Birds: acute and chronic toxicity - Fish: acute and chronic toxicity • Toxicity testing in animals (28 tests) - Acute effects of single doses - Chronic effects of lifetime exposure - Effects on reproduction - Mutagenic effects - Carcinogenic effects during lifetime exposure Summary of Data Requirements for Registration (continued) • Plant protection (8 tests) - Germination, emergence, vegetative vigor - Aquatic plant growth • Re-entry protection data (4 tests) - Foliar and soil residue dissipation - Dermal and inhalation exposure • Non-target insect data (3 tests) - Honey bee acute contact - Honey bee toxicity of residues on foliage - Field testing for pollinators Label Means Different Things to Different Groups To the manufacturer: It is basically a “license to sell” To regulatory groups: It is a way to control distribution, storage, sale, use, and disposal To the user: It provides information on how to use the product, correctly and safely To the physician: It is a source of information on proper treatment for poisoning cases Types of Labels • Section 3: basically the regular federal label. • Section 24c: also called a SLN label (Special Local Need). This section of FIFRA specifies a state may provide registration for additional uses of federally registered pesticides to meet a special local need. Special local need defined as “an existing or imminent pest problem within a state for which the state lead agency has determined that an appropriate federally registered pesticide is not sufficiently available.” paver) Bayer CropScience Sencor® DF 75% Dry Flowable Herbicide Bayer CropScience LP For Use on Soybeans P.O. Box 12014 EPA Reg. No. 264-738 2 T.W. Alexander Drive Research Triangle Park, North Carolina 27709 EPA SLN. No. NC-840005 1-866-99BAYER (1-866-992-2937) Attp://www.bayercropscienceus.com 24(c) Supplemental Label FOR DISTRIBUTION AND USE ONLY WITHIN THE STATE OF NORTH CAROLINA It is a violation of Federal law to use this product in a manner inconsistent with its labeling. This label must be in the possession of the user at the time of pesticide application. Follow all applicable directions, restrictions, Worker Protection Standard requirements, and precautions on the EPA registered label. Refer to EPA registered product label for Sencor® DF, EPA Reg. No. 264-738, for chemigation instructions. SOYBEANS. Sencor® DF 75% Dry Flowable Herbicide may be applied as a preemergence overlay application following a preplant incorporated treatment of Treflan® for the control of sicklepod in soybeans grown in coarse textured, low organic matter, coastal plains soils. Refer to the federally registered label for appropriate directions for use, recommended applications and special precautions prior to use on these soils. RECOMMENDED APPLICATIONS Sencor® Overlay Application Following Treflan Applied Preplant Incorporated: Sencor® DF may be applied at the rate of 1/3 Ib/acre as directed on the label as a preemergence broadcast or band overlay application on coarse (light) soils following a pre-plant incorporated treatment of Treflan® E.C. at the rate of 1 pt/acre. Consult the Sencor® and Treflan® labels for specific directions for use, recommendations and restrictions and for additional weeds not specified on this label. Do not use on coarse textured soils, (loamy sand or sandy loam) with less than 0.5% organic matter or sand with less than 1% organic matter. Types of Labels • Section 3: basically the regular federal label. • Section 24C: also called a SLN label (Special Local Need). • Section 2 (ee): allows application under certain conditions not specified on label • Section 18: emergency exemption Under FIFRA Section 18, federal and state government may be allowed the use of a pesticide in emergency conditions, where EPA has exempted the pesticide from the requirement of registration. An emergency condition is defined as an urgent, non- routine situation that requires the use of a pesticide and is deemed to exist when: 1. No effective pesticides are available that have labeled uses registered for control of the pest under the conditions of emergency; and 2. No economically or environmentally feasible alternative practices which provide control are available and the situation involves the introduction or dissemination of a pest new to or not theretofore known to be widely prevalent or distributed throughout the United States, or will present significant risks to human health, or will present significant risks to threatened or endangered species, beneficial organisms, or the environment, or will cause significant economic loss due to an outbreak or an expected outbreak of a pest, a change in plant growth or development caused by unusual environmental conditions where such change can be rectified by the use of a pesticide. Emergency exemptions are requested by the state, and approved by the EPA. Data supporting the need for the exemption is submitted to the EPA prior to the approval, which can take up to three months. Once an exemption is approved, labeling must be in hand during any use of pesticide granted a Section 18 Emergency Exemption. Emergency exemptions are time limited, and are generally granted for one-year time periods. EPA Approval of Labeling • EPA has certain labeling information requirements and must approve all language proposed by the manufacturer • EPA reviews labeling to make sure use it contains the information needed for safe and effective use of the product • Labeling supported by toxicity, residue and environmental data from manufacturer • EPA must approve any changes in labeling Trade name u,> Type ¥ pesticide ORTHENE 90 S$ (INSECTICIDE) (INSECTICIDE IN WATER SOLUBLE PACKETS) Active Ingredient By Wt. Acephate (O,S-Dimethyl acety/phosphoramidothioate) cece eee eteeeeee 90% Other Ingredients —.......... cee 10% Formulation for Eggs/DEADHATCH® EPA Reg. No. 59839-33 EPA Est. 39578-TX-01, 39578-TX-01©), 67545-Az-01(6) KEEP OUT OF REACH OF CHILDREN CAUTION PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS & DOMESTIC ANIMALS CAUTION Harmful if swallowed. Causes eye irritation. Avoid contact with eyes, skin and clothing. Avoid breathing dust or spray mist. Wash hands thoroughly after handling. Do not allow children or pets to come into contact with treated areas until sprays have dried. FIRST AID Acephate is an organophosphate, cholinesterase inhibitor. If swallowed: Call poison control center oF doctor FIRST AID (Continued) NOTES TO PHYSICIAN This material contains a cholinesterase — inhibitor. Measurement of blood cholinesterase activity may be useful in monitoring exposure but decisions regarding treatment will usually need to be made before test results are available. If signs of cholinesterase inhibition appear, atropine sulfate is antidotal. 2-PAM (PROTOPAM) is also antidotal and may be used in conjunction with atropine but should not be used alone PERSONAL PROTECTIVE EQUIPMENT (PPE): Applicators and other handlers must wear: long- sleeved shirt and long pants, waterproof gloves, shoes plus socks and chemical-resistant headgear for overhead exposure Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. USER SAFETY RECOMMENDATIONS: Users should: + Wash hands before eating, drinking, chewing gum using tobacco or using the toilet . Remove clothing immediately if pesticide gets inside Then wash thoroughly and put on clean clothing. . Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing Parts of a Pesticide Label 1. Product name, or trade name 2. Type of pesticide 3. Use classification General use Restricted use General Use vs Restricted Use • Anyone can purchase and apply a GU pesticide. • Only licensed applicators may purchase a RU pesticide. • Only licensed applicators, or someone working under the direct supervision of a licensed applicator, may apply a RU pesticide. 12069D1-10 RESTRICTED USE PESTICIDE due to groundwater concems. For retail sale to and use only by Certified Applicators or persons under their direct supervision and only for those uses covered by the Certified Applicator’s certification. INTRO Preemergent Herbicide By Monsanto Emulsifiable herbicide for weed control in soybeans, peanuts, grain sorghum (milo) and crops listed. The use of this product may be hazardous to your health. This product con- tains alachlor, which has been determined to cause tumors in laboratory animals. In case of an emergency involving this product or for user safety information on this product, Call Collect, day or night, (314) 694-4000. Complete Directions for Use OR DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT (INCLUDING CLAIMS BASED I CONTRACT, NEGLIGENCE, STRICT LIABILITY, OTHER TORT OR OTHERWISE) SHALL BE THE PURCHASE PRICE PAID BY THE USER OR BUYER FOR THE QUANTITY OF THIS PRODUCT INVOLVED, OR, AT THE ELECTION OF THIS COMPANY OR ANY OTHER SELLER, THE REPLACEMENT OF SUCH QUANTITY, OR, IF NOT ACQUIRED BY PURCHASE, REPLACEMENT OF SUCH QUANTITY. IN NO EVENT SHALL THIS COMPANY OR ANY OTHER SELLER BE LIABLE FOR ANY INCI- DENTAL, CONSEQUENTIAL OR SPECIAL DAMAGES. Buyer and all users are deemed to have accepted the terms of this LIMIT OF WAR- RANTY AND LIABILITY which may not be varied by any verbal or written agreement. PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals Keep out of reach of children. DANGER! PELIGRO! Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) CORROSIVE. CAUSES IRREVERSIBLE EYE DAMAGE. CAUSES SKIN IRRITATION Prolonged or frequently repeated skin contact may cause allergic reaction in some individuals. This product may cause skin sensitization reactions in some people HARMFUL IF SWALLOWED. HARMFUL IF INHALED. Avoid breathing vapor or spray mist. Do not get in eyes, on skin or on clothing. FIRST AID: Call a poison control center or doctor for treatment advice PULL HERETO OPEN > RESTRICTED USE PESTICIDE DUE TO TOXICITY TO FISH AND AQUATIC ORGANISMS FOR RETAIL SALE TO AND USE ONLY BY CERTIFIED APPLICATORS, OR PERSONS UNDER THEIR DIRECT SUPERVISION, AND ONLY FOR THOSE USES COVERED BY THE CERTIFIED APPLICATOR'S CERTIFICATION. GROUP [EMM INSECTICIDE Karate Insecticide Active Ingredient: Lambda-cyhalothrin’: [10(S*),30x(Z)]-(+)-cyano-(3-phenoxyphenyl)methyl- 3-(2-chloro-3,3,3-trifluoro- 1-propenyl)-2,2-dimethylcyclopropanecarboxylate........... 13.1% Other Ingredients: 86.9% Total: 100.0% Karate Insecticide contains 1 pound of active ingredient per gallon and is an emulsifiable concentrate. 'synthetic pyrethroid Contains petroleum distillate.  4 PULLHERE TOOPEN B= 4 , Ww W Pennant MAGNUM’ Herbicide For weed control in nurseries, turf, and Jandscape plantings Active Ingredient: S-metolachlor (CAS No. 87392-12-9) 0.0... eee eee 83.7% Other Ingredients: 16.3% Total: 100.0% Pennant MAGNUM contains 7.62 Ibs. active ingredient per gallon. KEEP OUT OF REACH OF CHILDREN. CAUTION Not for Homeowner Use See additional! precautionary statements and directions for use inside booklet. EPA Reg. No. 100-950 EPA Est. 070989-IA-001 Product of Switzerland Formulated in the USA SCP 950A-L1E 0303 4, 1 aallon  e«*) Bayer CropScience OSPREY™ Herbicide A Herbicide for the Control of Annual Grass and Broadleaf Weeds in Fall- sown or Winter Wheat ACTIVE INGREDIENT: S- TOTAL: 1000% *This product is a water dispersible granule containing 4.5% of active ingredient, Mesosulfuron-Methyl, by weight. E.P.A. Reg. No. 264-802 E.P.A. Est. No.65387-AR-001 KEEP OUT OF REACH OF CHILDREN CAUTION Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577 For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937) FIRST AID IF IN EYES: « Hold eye open and rinse slowly and gently with water for 15-20 minutes. * Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. * Call a poison control center or doctor for treatment advice. | @ Unknown Zone What is a CAS number? • CAS number is a unique numeric identifier. Designates only one substance. • More appropriately called CAS Registry Number • CAS stands for Chemical Abstracts Service, a service of the American Chemical Society • American Chemical Society indexes and compiles abstracts of worldwide chemical literature called “chemical abstracts” Parts of a Pesticide Label 1. Product name, or trade name 2. Type of pesticide 3. Use classification 4. Ingredient statement 5. EPA registration no. and establishment no. and name and address of manufacturer Parts of a Pesticide Label 1. Product name, or trade name 2. Type of pesticide 3. Use classification 4. Ingredient statement 5. EPA registration no. and establishment no. 6. “Keep out of reach of children” (or KOOROC) and signal word Every label must say “Keep out of reach of children” regardless of its toxicity or signal word 6 (fe) Bayer CropScience OSPREY™ Herbicide A Herbicide for the Control of Annual Grass and Broadleaf Weeds in Fall- sown or Winter Wheat ACTIVE INGREDIENT: Mesosulfron-Methyl* {GAS No! 208465229-8))... cies sen scsvessiesseans ox secsnesipeisistivetpevecnnand eng vinusad ensawenes exsexsesptno teocvadt ong oebaieiite 4.5% INERT INGREDIENTS: 20... ceceecceecceeeese cesses cae coee cesses serene case cen seesaessaseceneceeecenesesstsceeseneeeeseeaaueaeueetesseaeseaeeceeeeenanenes 95.5% Protected by U.S. Patent No. 5,648,315 and 5,688,745 TOTAL: 100.0% *This product is a water dispersible granule containing 4.5% of active ingredient, Mesosulfuron-Methyl, by weight. E.P.A. Reg. No. No.65387-AR-001 KEEP OUT OF REACH OF CHILDRE Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577 For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937) FIRST AID Hold eye open and rinse slowly and gently with water for 15-20 minutes. * Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. * Call a poison control center or doctor for treatment advice. IF IN EYES: . What Are Signal Words? What Do They Mean? Signal Word Toxicity Approx. adult Oral LD50 Caution Low toxicity 1 ounce to greater than a pint Warning Moderate toxicity 1 teaspoon to 1 tablespoon Danger* Highly toxic Few drops to 1 teaspoon *In addition to the DANGER signal word, the word POISON and the skull and crossbones must be displayed on labels of products that are acutely toxic via oral, dermal, or inhalation exposure. Statement of practical treatme OSPREY™ Herbicide _ A Herbicide for the Control of Annual Grass and Broadleaf Weeds In Fall- sown or Winter Wheat ACTIVE INGREDIENT: Mesosulfuron-Methyl* (CAS No.: 208465-21-8)............ ie: . 4.5% INERT INGREDIENTS: ..........00sssscsssscccessescssessinssseeansesse i iad 95.5% Protected by U.S. Patent No. 5,648,315 and 5,688,745 TOTAL: 100.0% *This product is a water dispersible granule containing 4.5% of active ingredient, Mesosulfuron-Methyl, by weight. E.P.A. Reg. No. 264-802 E.P.A. Est. No.65387-AR-001 KEEP OUT OF REACH OF CHILDREN CAUTION Si usted no entiende Ia otiqueta, busque a alguien para que se la explique a usted en datalla. (Ifyou do not understand the label, find someone to explain it to you in detail.) For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577 For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937) FIRST AID IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for treatment advice. IF SWALLOWED: Immediately call a poison control canter or doctor for treatment advice. Do rot induce vorniting unless tald to do so by a poison control canter or doctor. Have person sip a glass of water if able to swallow. Do not give anything by mouth to an unconscious or conwulsing person IF ON SKIN OR Take off contaminated clothing. CLOTHING: Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control cantar or doctor for treatment advice. For MEDICAL Emergencies Call 24 Hours A Day 1-800-334-7577. Have the product container or label with you when calling a poison control canter or doctor or going for treatment. PRECAUTIONARY STATEMENTS CAUTION HAZARD TO HUMANS AND DOMESTIC ANIMALS Harmful if swallowed or absorbed through skin. Causes maderata aye imitation. Avoid contact with skin, eye or clothing. Wear Parts of a Pesticide Label 1. Product name, or trade name 2. Type of pesticide 3. Use classification 4. Ingredient statement 5. EPA registration no. and establishment no. 6. KOOROC and Signal Word 7. Statement of practical treatment (i.e., first aid) and note to physician for more toxic products Gramoxone Inteon™ FIRST AID Contains Paraquat, a Bipyridylium Herbicide If swallowed SPEED IS ESSENTIAL. Immediate medical attention Is required. If available, give an adsorbent such as activated charcoal, bentonite or Fullers Earth. Call a poison control center or doctor immediately for treatment advice. Do not give anything by mouth to an unconscious person. If inhaled Move person to fresh air. The odor of this product is from the alerting agent, which has been added, not from the paraquat. If person is not breathing, call 911 or an ambulance. Call a poison control center or doctor for further treatment advice. If In eyes Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remave contact lenses, if present, after the first 5 minutes, then continue rinsing eye Calla poison control center or doctor for treatment advice. If on skin or Take off contaminated clothing. clothing IMMEDIATELY wash with soap and water and rinse for 15-20 minutes. Prolonged contact will cause severe irritation. Contact with irritated skin or a cut or repeated contact with intact skin may result in poisoning. GET MEDICAL ATTENTION. Call a poison control center or doctopfomerestment advia NOTE TO PHYSICIAN Refer to.te'Wooklet ‘Paraquat Polsoning. A Practical Guide to Diagnosis, First Ald and Hospitab ar€atment’ (httpuwww.syngenta.com/pqmedguide/}. Administer either activated charcoal (100g for adults or 2g/kg body weight in children) or Fuller's Earth (15% solution; 1 liter for adults or 15ml/kg body weight in children). NOTE: The use of gastric lavage without administration of an adsorbent has not shown any clinical benefit. Do not use supplemental oxygen. Eye splashes from concentrated material should be treated by an eye specialist after initial treatment. With the possibility of late onset corneal ulceration, it is advised that patients with paraquat eye Injuries are reviewed by an eye specialist the day after first presentation. Use treatment that is appropriate for chemical burns. Intact skin is an effective barrier to paraquat, however contact with Irritated or cut skin or repeated contact with intact skin may result in poisoning. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. HOT LINE NUMBER For 24-Hour Medical Emergency Assistance (Human or Animal) ‘Or Chemical Emergency Assistance (Spill, Leak, Fire or Accident) Call 4.5000-882,837? PRECAUTIONARY STATEMENTS. HAZARDS TO HUMANS AND DOMESTIC ANIMALS: DANGER / PELIGRO PPE is what the applicators and handlers must wear; Minimum for any pesticide is long-sleeved shirt, long pants, shoes and socks. From the Staple LX label From pages 1 and 2 of Osprey label In addition to the minimum of long-sleeved shirt, long pants, shoes and socks, this label also requires chemical-resistant gloves and protective eyewear. From Gramoxone Inteon label In addition to the minimum of long-sleeved shirt, long pants, shoes and socks, this label also requires chemical-resistant gloves, protective eyewear, and a respirator. Gramoxone Inteon™ Mixers and Loaders must wear: * Long-sleeve shirt and long pants * Shoes plus socks * A dust mist NIOSH-approved respirator with any N, R, P, or HE filter * Chemical Resistant Gloves - Category A (e.g. barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinyl chloride (PVC) or viton) * Chemical resistant apron * Face shield Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/ maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. Engineering Controls When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. User Safety Recommendations Users should: « Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. « Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. © Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Environmental Hazards Wildlife: This product is toxic to wildlife. Do not apply directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment washwaters. From page 2 of Osprey label Minimum environmental hazard wording on any label. From AAtrex 4L label Ground and surface water issues More environmental issues Parts of a Pesticide Label (continued) 9. Directions for Use Statement on Use Contrary to Label Storage and Disposal Agricultural Use Requirements (WPS) Engineering Statement (WPS) From page 2 of Osprey label Statement on use contrary to label From page 2 of Osprey label Standard wording, all labels REI PPE for early entry From Clarity label Storage and Disposal DO NOT contaminate water, food, or feed by storage or disposal. Open dumping is prohibited. This product may not be mixed, loaded, or used within 50 feet of all wells including abandoned wells, drainage wells, and sinkholes. Pesticide Storage: Groundwater contamination may be reduced by diking and flooring of permanent liquid bulk storage sites with an impermeable material. Store in origi- nal container in a well-ventilated area separately from fertil- izer, feed, and foodstuffs. Avaid cross-contamination with other pesticides. Pesticide Disposal: Wastes resulting from this product may be disposed of on site or at an approved waste clis- posal facility. Pesticide, spray mixture, or rinsate that cannot be used according to label instructions must be disposed of according to federal, state or local procedures under Subtitle C of the Resource Conservation and Recovery Act. Improper disposal of excess pesticide, spray mix, or rinsate is a violation of federal law. Container Disposal: * For Plastic or Metal Containers: Triple rinse (or equivalent) and add rinsate to spray tank. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration, or if allowed by state and local authorities, by burning. If burned, stay out of smoke. * For Bulk and Mini-Bulk: Return empty container to point of purchase for repackaging or recycling. Parts of a Pesticide Label (continued) 9. Directions for Use Statement on Use Contrary to Label Storage and Disposal Agricultural Use Requirements (WPS) Engineering Statement (WPS) Application Sites, Timing, Adjuvants, Methods, Mixing Instructions, Pests Controlled, Application Rates, Tank Mixes, Sprayer Cleanup, Rotational Restrictions From page 2 of Osprey label STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. PESTICIDE STORAGE Store in a cool, dry place. PESTICIDE DISPOSAL Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. CONTAINER DISPOSAL Empty containers should be triple rinsed (or equivalent), then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration; or, if allowed by State and local authorities, by burning. If burned, stay out of smoke. From pages 3 and 4 of Osprey label Application Methods Mixing Instructions From pages 4 and 5 of Osprey label Weeds controlled, application rate From page 5 of Osprey label (continues on page 6) Equipment Cleanup Procedu From page 7 of Osprey label — = =~=—She™~ TANK CLEANUP PROCEDURE 1. Draltrtteterieeerrpletely, and then wash out tank, boom and hoses with clean water. Drain again. 2. Half fill the tank with clean water and add ammonia (i.e., 3% domestic ammonia solution) at a dilution rate of 1% (i.e., 1 gallon of domestic ammonia for every 100 gallons of rinsate). Complete filling of the tank with water. Agitate/recirculate and flush through boom and hoses. Leave agitation on for 10 minutes. Drain tank completely. Repeat step 2. Remove nozzles and screens and soak them in a 1% ammonia solution. Inspect nozzles and screens and remove visible residues. Flush tank, boom, and hoses with clean water. Inspect tank for visible residues. If present, repeat step 2. SPRAY DRIFT MANAGEMENT OSPREY™ Herbicide is not volatile. Damage to sensitive crops can occur as a result of spray drift. Spray drift can be managed by several application factors and by spraying under the appropriate climatic conditions. Consequently, avoidance of spray drift is the responsibility of the applicator and grower. SENSITIVE AREAS: The pesticide should only be applied when the potential for drift to adjacent sensitive areas (e.g., residential areas, bodies of water, known habitats for threatened or endangered species, non-target crops) is minimal (e.g., when wind is blowing away from the sensitive areas). Avoiding spray drift at the application site is the responsibility of the applicator and grower. The interaction of many equipment-and- weather-related factors determine the potential for spray drift. The applicator and the grower are responsible for considering all these factors when making decisions. Do not apply under circumstances where possible drift to unprotected persons or to food, forage, or other plantings that might be damaged or crops thereof rendered unfit for sale, use or consumption can occur. Rotational Restrictions ROTATIONAL CROP RESTRICTION From page 8 of Osprey label CROP ROTATION INTERVAL Wheat 7 days Barley 30 days Sunflower 30 days Soybean 90 days Cotton 90 days Rice 90 days Lentils 90 days Dry Beans 90 days Peas 90 days Peanuts 90 days Corn 12 months All Other Crops 10 Months. OSPREY™ Herbicide is degraded by microbial action. Under adverse condition such as cold temperatures and drought, degradation may be slowed. It is recommended that a field bioassay be run when adverse conditions occur. Grow test strips of the desired rotational crop in the fields previously treated with OSPREY™ Herbicide. Results will indicate if the rotational crop can be grown. Parts of a Pesticide Label (continued) 9. Directions for Use Statement on Use Contrary to Label Storage and Disposal Agricultural Use Requirements (WPS) Engineering Statement (WPS) Application Sites, Timing, Adjuvants, Methods, Mixing Instructions, Pests Controlled, Application Rates, Tank Mixes, Sprayer Cleanup, Rotational Restrictions Precautions for Use Drift Management From page 7 of Osprey label (continued on page 8) Drift Management From page 8 of Osprey label (continued from page 7) Parts of a Pesticide Label (continued) 9. Directions for Use Statement on Use Contrary to Label Storage and Disposal Agricultural Use Requirements (WPS) Engineering Statement (WPS) Application Sites, Timing, Adjuvants, Methods, Mixing Instructions, Pests Controlled, Application Rates, Tank Mixes, Sprayer Cleanup, Rotational Restrictions Precautions for Use Spray Drift Management Other: Resistant Weed Management, Endangered Species,