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Notes on Aldehydes and Ketones - Elemental Organic Chemistry II | CH 232, Study notes of Organic Chemistry

Chapter 16 Notes Material Type: Notes; Class: Elem Organic Chem II; Subject: CH-Chemistry; University: University of Alabama; Term: Fall 2012;

Typology: Study notes

2011/2012

Uploaded on 10/25/2012

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Download Notes on Aldehydes and Ketones - Elemental Organic Chemistry II | CH 232 and more Study notes Organic Chemistry in PDF only on Docsity! C na pter Ilo : Al dehyde - Cefones He 2 16,15, (¥ 20-24, 27-33 94, 37,40 ,4/-A3, 46-47, 57 $2 74, %, 54, 6%, 65 68, 73,74 Fb , te ~ re - ree ents NC ON. ttt yt ae Strectre Benchig ner 62 Mdebydes ¢ ICedones p L, any us- fer ff ak dehyde [Lefer —y (a i oT benz Ldehreke VF Y (6)-3 penta Drone, 6 cy’ Cyeloherene C ar hblelde 6 ae ~ [ C | bona nage G (4hophenany an fo ) es, => "Ne edively Charged ©.4 ©, Sp Be Ss AH, a7 OR , “CEY “—) Newhrul Oe | Hor , MHS, R, We &) There ae 2. genersd reechion pothwunys ( Sor nucleo phi IK ade Lim +o 44 alels horehe of cetone. i ~ © 5 aren i pts R b ~ Mae f ate 2) tg i Y vet ahes 1 Mac [ 7 5) pre’ tel ion 0/ ees gan TA eget a yt Addition of o Car bon nucleaphi s ee sayy eam ne Gf) fori neared Kes pods — aa 5 N) Adel tion " KAM fe ow O op Pox © i Hd / Hao ou a ee =) Add Jon. oF 4 Grynsel fey eat " Dr mele hyde panuirkes d ~ © eae’ (© =? Surnshes g 2°- atcohet 3) Add toon ot R-Ayx 9 leetons t R v 9 ‘Ay n-M a LTRS Q Ap nanan Re of j co i pep 2 Be ni me provides q 2 oales hee! @ & Add chin of Ht ikea of HY o ean 4 bw iv ew % a - sw ack, f ee. , » os ey ~ H wy ~ | v ¢ aX “ | yo oO & b G5 te & be (hired ix, @ Af G cc aber a : é oy ates Ihe a! “wy cant s | ) <e a ne tidy ¢ / ary HA Pe lle (o> 7 lus Lee feactian @ The losthy feechon =) The Writa ye echo rans forms q Car bor (alelthrede or ketone.) ino an aflcene Senay aren cainnrnin OO -« Lo ph,P— che A pees = Addktron of the ylide (2, PB) fo the carbom! followel by ePrmintion of Phy P=? abbas for the synthess of deh Coltes ponding al bene. he WiHiy reaction fakes plee ™ 2. Steges, (1) Corny OM ¢ Shructore of pha Phosphonium yi ) PhP. Cd, ze “ ——? Phy P ‘a, neta] typheny| wv P hosp hort ww ele i ° © b ) ) 182, el p Q Te Oo, han ai | le Pole (e aca a ~ auc ops e ‘le fady B fo ache 4y the Car rbarey| vl & Stere ochemotoy ot the YA Hig. (eachon | clelehydles == 4 prokly when ane up! VUeS FH wl vr Phot an Gren debe [roy up he ad bene Sfeyeschems shey has 4 hap her Ble rede. i ae cane 6060 wn p h oo u _Ph: or, Phe ALP Z f P bA~ce 87% 13% = the ofppos.}* holds trae one hes 9H Gnwn Shovlie dy fry oS Part ot She. splioke ba 8 apt 6 ab an ea pay PPS phe Koch These “Stebiliond y hic Qre less peeopue ¢ hypicMy only fest wv aldel~des. => -The netre of 4 sta bcliret y like 5 the 34 fe Sonen ae, Shtacture, i OD os _ @ pP hyP 4 fanny PL 3 pS? of ~ Oe De ee od d Pry > Pry P Q @ (6) Add: _ of Ong MK re n fAscleogey . + Te ie we isan sano few 2? ote poy ap ot ao-tt oP ao os f | ‘ee ae be “Ole “ per gate? oe 406 oh f “ou L A F (2 Add Gignedd b> benz Pdehy dd 4) Qarach »/ H,o® fe reywove. cee tteal v Ya ton & fhe Wewaly Larmeck Lore ced Qurcdy @ea o” 2 ios 4 5 H30 ee sop Any &f) tdhen Yn inlets abot Synthes® | One Can uh Ree ’ ahh as Plotecting por for MCebones & abele hyd es ZO) Addsrion ot Mregen Muclephils: Lorine t Endmint Locmat on ceccnaparcn eI AON eh err BH Primary arnines (Ranta) add te abide byes & [Cetons odes Grn fmines, 2% “a 9 nie i pore’ a oR + He? imine OB Secondary amines (2H) ade te odldelycls t erenes te arm Charms Mechansem coh ming Lormahon OE) Recll , alelehrole [betwee a cng hy He “ek fern Hie ip be Ne bade fie i “ er # Carbiaed amlag ene 7 Reusysible «ie cabled proces mings, (22 Nei eerste eR rou scnerecescon wane Oxrdation of aldehydes df Ketones - 6 6 i) eae EN pe ton st 40 0 | TH as mm, ~of a H oe OQ (eteng => takes plece under ack Cogn) bie B An cdtenukive 3 frat oy uses Ay. In Alte H & hows cla Vole holes oxvedlize fo Cathe wy !® acrd $2 (2) = aldehyk orielatin oc vig the Aycaded a ohyde , One ihe e hycle & Cormecd, Rod re ts then Oxi ie-e hy a MAME r Shmolee te pot of g 2°-o4 fo Q |ewpne wo ernment COTA remenerrsnt Soa N OSA mR GOTO pontine ities AAAs rege eM kee Reel ucfons e £ aldehyedss & | Late wé§ eenarpsecieat &® Mdekydes ‘aerate arn ca 0 pp. o# fl de My LHS ae al of a hyeke =D | Oo Ley bro ao ) yee 0 , _ pe it VF ah OS oH “ z) 432 - ee) [Cerene. pecduction ee ntnte tnntne ott hk mene of I 2 Wa b Hy fn AL 2) id > oe fo}
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