Organic Chemistry (Halogens,alcohols ,ether,ketone etc), Summaries of Chemistry

Download Organic Chemistry (Halogens,alcohols ,ether,ketone etc) and more Summaries Chemistry in PDF only on Docsity! ‘YShowr Chaim isomerism egy Spb hybwa (vea?2e") i) Heteds of Hon a) From umiatuneded Hydrocore] (ethene omd etryme D(a} ey Pe) Som Wurtz Rexction (Oy She) 9) Grty-House Rerction (Pry ott] 3) Reduction of alkyl hatdortey 4) Grignord Reagents (Dry other) C (erboyylie actdy Detortory fation (Cao, £30k) b) Rothe s eleerrclytic qetiod d) Fem atotols , aldehytes omd Retones (Red P , 423,103,7} CHEMICAL PRoPERTIES D SLEVIN REACTIONS x» Heaton cose Ctw #y $30-btek) by) Nidvaten (723 £) ©) Sutphonation (23 aie) (673.9 D Ox DATION) ae ) CtokyHe bridadtior, ite (cu- tube [100 etm y HIZR Oy on Chain and Posikey fsomens Greormetrteat , Hemens (Cty ort tranf a) Sh hybrid (120°) Ny Peshraiters pay oa” @) From Atkymes (rinabys aul CNe [Uy Nig +e give tons) 9 Fen atcahata (tone Hy sou 433-UuaR ) Rom, Athy & Hatides (ale. Kon’ SATEFPs RULE A) Rom Vidnar Dihatides C2m + ethavet) ©) Diterbowy tic anid ( Robbe! Chertaly te meted ) CHEMICAL PRoPERTIET IO AodiTICN REARet jens a) Addition 4 Hycngen (Ni or Pt) by Raditen of Hatogoml[Cety J €) Addimer, of Halogen acids C hydro betasentch Gm) e MAR ow WIFE Ss RULE Sy KHARSH Poroxide Yee W teats d) Addition of Waloy (HydcHen), 4) Oy [5432 Moy O 4 tovatm JY ©) Addition | Hypodaton eels | d) Adsusios. oc] SUlPhioic acid SYLLABLE Y Chain, positon awd 6g But-2yme and Bus 1,3-dione i) sp (1@0*) ; rity Pabere ters Ale; Kon ) 2) Delhydae halogoration of 142 halides (vicinal dihatiatsy by) Dehydrohalogoration of ty(-dd hotdes (At. por) ©) Delatogeratton 4 tetra belid al ( Zntpethancl ) dy Rom Aeetyleme @) Rowbe hic hdy tre emetinod CHEMICAL Properties re ® Adorriow REActIONS a) AddiHon of Hydregon CH3) b) Addinow ° Hatogou (mee -s tose C) Redden of huteon acts Cia) Ay Addi Hon of, Water Chy chalion) Cg Sen Bnd PLE Hy sou) ) Adajon of Hybotatou aera Chee) 1) Aetdisren of Hycregon Cyanide BENZENE ord by Retovamee Mructives Vi) Keble steve ond Orbliah stuckwe of beusone th) Prebovartene _&e 2) From Sedlim, Benzeate. b) From Phoned (zn) (Drsxltoten) ©) Rom bergene Stlphonicaes, Chee 4463-4232) = ]8) Bom Benzene digontting Ake de “|@) Pom <0etyLeme CSyminents ) CHEMICAL PRepenries: MD Aopition REACTION seuas-sw ke Q) AddliHen of Hyshrogor, ( siier At) b) Addy Hom Halegens Chv) Crsevtsle) (Bue) (Undone) © Aadision of ore aa Si UANib ql cere Doll ‘Hatta ) CLemusle ) 6) Fenanesranion UPyRouysi nN ey CRACK cea ont e +e PHehe Fethimre wichon ’ tareny Fy TWBethone fo Bene + moline ey Ti) DOtome do Meblane + Ryienotot| D Som ERISATION ALcts +HER eaviae tor bulges: #HNER 3 S5ciny { © Aromatisaniow Gukekene Sy Bengone tu ; Nek Cr,0, Gnoauanons a) Staggered rfevemell oy, b) Elipsed Crformatio, (SD FgoM ERisaTien Ss © Rey nerisanion REnerions @® oxidation RMcrons | a) yy bU-H ow b) Oxidation With RM ny fy DLA RMQOy omnd colt (299-34 CBaeyeves tort) Hi) Hot cmd tone. knmoy (H-39i] IO) Oxidation Utltlh ozone, I+, 0) a) Palymeviselton of Heme (Sono b) Potymertsaton of Vin & Chloveld ©) PaLinmertecn, Tehefloine Cherenie J A) Pedyoneyrtertion. 4 Shyrene KD Sussttromon Reactien © OXWanon | RERCHONS 4) @mbuten b) OxtoaHoyn UH KMyoy t) Ditute aqadhyet ty bedme Cag- 303 ky HN) Hot ond Con. athdine Krnal Gi3- a» my tee Seid Lorn ©) Oronstysis hb) Can +H05 ia Dilyomortecetan of ety lane Ged hor hon debe) AD ACDIC SE characrER 4 Athy| ey Reathen” uit, NENT 6) WP Ammontets? Gee’ 6) Bmmentack AjNo, ‘ Laberctory Pref oetien, © POLYMERISATION REAcHeN Cy + 2H —> Galery, +0¢0}" OQ Suestitumiond REAGnow' Ky Hallogtnation (Fetes) by Nitvedion( Hy soy 3338) M" ©) Subphovetion( Hide.) We dy Fredep-Cralys rence, | y Ae obey me Crecesy 8 ii ) Freset- Crate ee . CARCRS [Dex pAnon REACHIONSS ) Gmbust on, by Custy ae Pe cere “TEST FoR 8ENZENE AReonancery ORECIVE INFLUENCE KERULE Stehire Qer erpred ge, Ore Won, Pee paration) i a ? 0 fon mana A or Pt sy Niorbe » ChyScH ayy SSS cy -ch, i") CHg- CH=CH 4+ Hs—9 CH Ch, Cry Eihowe rere Propewe W) Coy CECH oH, SYM 0H, cH Oy j Prebym e @® How | Alkye Halides DP AlkyR Hotides (oxcobt fLreicit) on reduction with =n ond Ate. HEE ghe Pasa e . ~ zn. CH-C2 +, SH, +Hee GUS cht Hy oa ey ee \ | ! ‘ a9] By Wurtz Racoon 855 ell BN vy, dy DWhen Ue, L ralice (Br or T) 1s Ca: Mike ee ay e a, bee + fi e olen, Ch erect solution, Syrmmeletap |XLROne Loyledry! fulce ® 4 oe REX +2 Nh +x7R PPS" BR 419 Nex & a | abhome y Ox- by Ch By +2Ne + CH Br avs “5 Chy—Ch, + 2M By Cytar +9 owe Hy Cy: Na + CHeCH, F 5 Cy U4, —Chy. ch 4 2NeT Buteme Li 4 - | ly i { When FOCH ng city ® halides one ay eye alaetave 6] free clare; is epee chy: { CH3 CH, + 2Ne + CH ey Org -CHS Ch, + Ne ‘ (Prpeme) Connpornds 4 type R-Mg -x CadLkaye anagn0st iene hoticte ) ove froin 8 Cudgrord Highty YeaeHve reagent ond wed Wy, Syndnestr of retely a] oe a Dey ether POG eee? iii CH CHa By + Mg TS” cag cry my By ethy fk Tragmeyiim byombche a Grgmera reader 4» the CMg bend ts Highs falow blz Covbon ston CdteChed 4o yt Mere Che eh srregeph dho~ ~ Bo, Grane veagra 1s healed with pe dovey ‘MRe Uatey nee ard» athyh poup cosh teith Jreton to give otkome . ran Boye fiton- —> Bus + tyloiox D Ong Che + Hy Con)By MERE. CH3 Chy My By + HOH » 8 Cees Cry Cry Br +24 PES”™ Cry capes + Libr (ebtryt Uthivnn) ACHCHLY + Ot —9 (eh dy Cour+ vit Li¢uivem ethyLioppey Cua c i CCh3 Cr) €ous HOCH CH h, ——> Cry CH, dy By Redueton ef athyR helices = & reducing ely k police Utd red phesbhars Mma Wed siese oa Rea Pts tyek 4o Weve focdine dovmned bn YeatH on @® Ghsbr 2H > Gig + ABy + CH, CH, Coy Ly Cyc + Kip MH Perio, ¢ Minfl coher / 2P + 35 —— 5 oft, P. © Gye Scere ! CiGesmyue eps be a % December syfetien Rerreve2 of & Apo (Coen) D Gy te Gried cut by heating aud with Sedollme(% Mnde | Nad Ord Cao Wr 321) Sheu. 680k," Cao Roone + reH = RH + NegCos GBoK Ae Cuz Coo H +-NROH —> CiyCooNa +Hyo Stdiunny CHorete Coedum) deokete) ChzCoon, 4+ Neon > Ch, + Na C2 630k (Bent cn acon + MoH —9 CyCHCoome + Hyo i a Propanucte \ Cry CryCoome + Nab £825 Cheers 4 thy Coz 63ole b) Kolbe elechalyHe Method 2 CH3CeeNa —~—> 2CH2Co0” +2.Net A+ anode t es es = A+ Cotiede’ 2Ch: Coo~ —5 2CHg Cos” + 2e Dike pe => eo Coos —? 20h, + 2002 2ou- +4, 1 Met Alwouys Conlodn ' DCH, => Cty ~ Cry fo. ae hen ¢ wed to Deh. odd mo. B) Fron, Alcohols, Aldehydes and Keroner | p t 1 R-OH +2HI od RH + + Ho PaCHO S26) ae Reb; 4+ 95 + Ho 73x yc=e eunr SPs R GHA! +25 + R So8h) i. Wh om Ho kia” | | ° - Ht Cg Ch, ——CHy pun) eee 4 8 woe 231 ? ae # 2Es +H 0° Ch3 CHo + yy, Pere eee Gy UB 1 pee + 2S +H ro PaysicAl Peorepnes O Fmterrmedocr lor forces excl 44 Dials | AAUBbL ep nc ounces dlev Weal’ force } @ Find uy grempe ove ght que eran ed Newt IB Laie end higher (Cg lent) salsa, > G) The! mmerecie me BP & duc go hacrene Tn ameletunter nos G2 ? OUCE CEL Cecscen aremnijucte of Vim der Waals Aorees - of 3 \ ) t “ i | i i due +o devene (iG reattes bremehing ef Ceo Power te B.P of frome ( eres deer e042 qyogrilude © Mbomes ove Seluby mo ipeby . Tsclubee 1, potes. Solvent the, leater, Ths: ts bez lalbone are nen pot GR (Wee CA ey ev mon peter Solvents . \CH ENICA LL: PRoPERT ES | , } | a HALOGENATION | cy, . hy O Ay CR eee CHs Ce +HER methyl cidoide | Cu3ce + &— > Cn, +0 on \ metry Lone chioide | Bromimokt Ch 6 $C, ES! Ch eHcg > wees plate 5 CHa eto apn anon a CY pues od e on Heracleorahe ne Say Pore fe ie nee cert oe odUmad1ey, EG OL a former rads lodockkona at oe a nal iCHy os Ss Cusx + Hi tock Into olkono, Ce wow Miia Hee en ty Provence a two, ak OS 2H +2HNo, — > TB + 2W0, + ono ' eer Bypass Hilo, > 3m + 3Ho D the preaerd o cowerting aUlphae Cn-hounds tide oxoale. sos ts Anon as Wont cotton, } C205,~ Alo ly CH, -Chy CH) Oh, -CH,-CH, 1 Aes un ) 3) ra Sy iD be Hy aa? A a N-hexome ) : \ byt Cty be MN) Chg CH, -CH CH, -CH Oye, bt 5 3 : 8 | Shon? lees Gn-hebrene > e73K THO CH Hy H et Uses oF ALKanes Ff OD sential Consipionts 9, a0 petrleut, Hears . @® les, eHhanes eve wed as CNG anal LPG } Higher by getline, diesel, Karcsone @ bebbrene js wed as Ariel Ord bt trend: a | Aienes) (mam 3 Umsedurkied Hy chboeavbew Conesrning one oy mrore Goubse bonek CGies Reye Avoum ay | okelns (elt jovming ) | j i SRLAVRE | | I i E me ht }) Tm ety one CHy =CHy both a | re 4 tI re Tener thal vol “p> hy byfdi ton mthoud (=z wy Say Ni Cae Resi hey | Q@ Geomedrcet Temevsrm Wher, duro Cornnfounst hoving i Trckecwtey fermnuta » Shmbfnr eboraltal Shrussines Onasl Geuble” bend possess oltferevct geowes Meh Uyengenments of the OF ey grou dhout doubly beveled Cybern odes , the phowencvan * note, Os G2evnel took feomervtson  Cis TRANS j i \ ) Buy -2-ene és See? ; eee OK, NH 7 ~e | Vy Bua-22ne, Weloclads| Aims aee/OeH Ua y arte a MAG Po teen tion Hl Ceo Prep RATION oF ALKENES @ Frown, Atky ner | > Ppenes tm be prabowed ‘by besa) ate Hryanes uit Glcutated Ovount of AU ydroger in preserve Ch pellodised Chercoak deaeHvated wit hotsoms Lhe gitmalme ey Stt phi Compounds - Deoctrered Paltnatred Bees mown a Undlors Re Crtelyse- eae Pasc AL wom ZR R-ceaR +H, SEs, aaa vedo, ' R 4 Bs re Pevttas nA R t = t Ca CH, = CH 4 Hy ee Cig Chen, Abe, © From AlLconors oon Hh =Ct, +H, © 2 Popov of Usatoy torfernd’ {yom tompotmal ts toed a1 Olehydiretter TH on! | R-C= CR) + Hy Ct tae Hy Se yh Cae ee eer +H,0 i in 433-443 R \ ’ HOW H Mecuanisn “ve ee h Ce, , beh fH" see ey, wy A i Cem aciet) Y Gj 4H ou Refomtes afiohel ©) Perm crvocoton Ho Coy > pobacHH + hyo lA { H aoe @) teges Poten <HeS re s ut hoe Bey we) eee eo + CQ Fom _Pubyh Teliees >) Atkomes_Com be prepared. by dlehydrobalogonaton o| othy.2 Halide. TH x di) | NA i heat f day + KoH PR-CHC-H + KX t+Ho Cabeatroticy Mi LB t Whats) te On exomple ef B- elminaHon KacHon bey hydrogen choy, ‘ mimated frown B-torbon OUuOVvn « Rate of yeaAtHey Bepords tt Hoe DT? ty >Os Cup Cy Br + Ro “Say scr, pee, ay, B27 WN) Chy Oy CH, > Rel—> C3 -H=Ch + kt +155 be On, H : 3 ) CW KOH By ¢ Be | Cyt CH=CH tee 4 Hro { "S0~ roby bovntete) SPYTZEPFSS Rove Fa Recording fo Say tpes Hated iy del drohalererosten' ol oki 0 halide Com Yield mee than ono CHROME) then wily product b mest Kigh2, Sibstuted alkenes. i ; are CH3 CH= CHCHy (rere Subphee}) CH3~ CH —CH= Cy Tiina} | efor practice by _— CHy Cay CH=CH) (Bus summer) E “bree Product 7 =D Dihalegen dernetve, vf otkenes fy white the two helogen clon, We present om neighboring Conborn Akos re “Gbked Udlrcl citslide | 4 7 Gis 0K as C-H + 2m —5 R-CHOH + Zn%> ft { Heat r ie i mp A I Cc wa G Ae ao 8 +2, BasiEts ae L2, Bx, Gy Pr Gin ; | | 2 ‘ @D A, Bah Zn Sse Cry —CH SCH, + 2B | dooh ol welbocs pe es of sells o) Di crboyyie Rerdy (Relbers Eletrdytie | \ \ Coe) C4,0oco7 € he ac se ee + 2k (terete Succlmote ) ue => Don- 4 a At Omecte) CH2Co0- —CH,coo> —9 Guy =Cly evo, ae At Cobtede 2H,» +26 - OXipATION REACTIONS fy Combuaton Buu wlth Mibwols Joye Et Cup =CHy + 30, —5 2CO) + BHy0 | Y) Ovidsten with boson perma 4amare o) Wit, Coll awd dilute Leno, I,2-dlols Rmoten os Wr cols Oye obtayned Bho (Hyder yhoo, of ebkornes ') ) CHy ec foe = +H.0 " 2 2 eo} 27, Ch, —Cny e J Pees WH nay T4HH, 5 “amy aor ne diel ‘ Sachs cnc) +2Mme, + 2K) Coty cot) San With het ool lomcemiretied | KemOy SolHon 373-393 5) =ChH, qer onlel@sed to Cornero (CH th, + 60 —> 2Co, hyo) ) och Ser 40 RoooH Cempexylic act 3338 = « ye a) (CH, =Cty -CH; +55, —9 Cyto +c0, WaeeR 4o Rae =o (ketene), |, CH , aha ne CUE St cH, so Cy Ge ae cis +, SAero Rrow~ os Oldayvye degedation- Ord buea to (Bertone) Ard +he pfosther el double bond Im om Unkrio wan ROW o = Bon © ona bond breoky OZoene0r1y 318 ; 3 oy psing OZMe ry om Inert Solvent (CHCO, oy CCQ) ethomes get swidtsed 40 evn Ozonide , Oronide oe Hnsielle gma ew plestve Compotnibs amd Sie rut Holated ron telation . raja they tad why gine srt Waley bo Give otelelydes cnn +} NX NAS 2nithe 7 Wc +03 —0 ad Cx a NEO 4 0 =CL Hy oy Qs .o a oN nits Hac 40 HCHO ( fovmeatdoryae) CH etn, to, SG St anche =e +H), ee oa C= % eh CH BON =o (olde de) 3~C= Ch) 40, Ch; ee noe ye i 9 fo tn, coat : R i WCK3CHo S R ( Se Bi cso Redon e ye +H Cho R Ro “Dy Be Qagey o7 , Poo ERGY BO on, Se chy Cu, Vesta! myo oy, . —Z d3>c=04+ Ghdio Ha ar Oz onely cis ts 4he bert mekhod Nag Doceds 4 beste. of dowtde BVA | uymerisan on, |, > whe, dorge we. of Slple anplocts lomnbwe 40 molecule devmn ts of very high molecule, may Uniley Sulsebls Expernontt Ando , Hre provets MN hmotin of polymaiston « Srnple meleotin eve Colles amonomer » ) Une Ee MCH= CH, BEE L CH, Oy chy} * Pobytnene K cnet H) Patymerseton | Vimy. Chloide Chtewettiane (viwel deve) OL his crt ch I ee eee nn SH CCl cH)! i Ti) Poly am ovsetion of fee os Choe High Penure HE Tojlen * Very dough policy mCBack ae. COG ~CB I, and $B rhe fo heok Om PEE Ctellowy Heo Attic, af ete Chemis ~ Fry reraplercetnaye ed Wy Curgteal dukes een - Is) fobs, omerttasron Savon eae trbing Uo weere TT Gry aegane oe st ua) ; at a i Styren | . , | Sbestre- tion) REACT OWS | - : CH, =¢h “Cy + Cg WS Cece ER +41¢Q CALL Chotel e ) SoMERISATON) MO Ee eae nee > C4, —CH = CH As “R-s7s py 3 ag Ch Shy tober Con. hes Sboreton Prepratie, Ch, = Cro =e CH=CH, + hho 32-4A3 Uses oF ALKenes SS towsey cthenes 04 fuels Bnet WULmImareds ® PoLy drone Nn +2/[fow rSymtheHe rubbew @® Patyides pening 4 doratds € Elny fre) 1) bust. fberCounn eenpuenalan aun eons [Aurynies | eat ae dehydrohalogenation of 1,)-t halides pebele Ate. kel Rc=cH ulate [tf ma gare ea PREPARATION eae owed vec. et f K The use A KOH gre wie Lt Meo en; Fey + DNNHD oy, MAS rewcttons Trorchere Sodamtd ; CNa NH te tued ) C3 -CEcH + Ne By TINKy O by Dehy ae of jo Uhabider’ i ‘ Ae. Ro cn, be -H > Ch,-c=CH + LHRy h by ® B eee es ef ee Ch, = } C-oH a 22n° by G) Rom Pee yftce ‘ 4, -O- Gus i H- a0 = Gn + Ch Ch, By ues Hc CCH, Cg + Nagy ©) By Rebbe vs eechdy tte method Bynmnol : 5 CH; -C= CH 4228, mee F : 1 it CHLoe le HCOOH jf. 5,4 ae a ; = ae a ¢ z 4 D1 At oreder Iho + 2e CHCee (2 Chtéoo Y : im H Cobbehe~ Creo — pn > ‘i > CHECH + 20d, 4 2e- CHC007 Arety Low e @ ADDITION REACTION 3 hase Frtpke bond prerevit: my albyme ECT IO Coruitts Of tuo me bendly » ath¥nes ove Loy TECHVE thay alkones 4ouerds elchapmire Feagents - Vy) Alkymes ore, nove Uabe, 40 be attacked ty Suchabitye eyed ( raxents Hating oxcey e-%) | | foLyMERISATION | Q) Poly am onisa ton of acer tone » we nk a ne MN ee iG Beoiiive We it) ucneen vem : 6 ad fe een veal _ it) Coreen 6 eee SO a SCH HCE CH (vinyh aeory fone) | meee Uy VI Ch, =CH— ¢ Fer tone aaa! CH HCH C=C CHE Gy o) PalyanercaHern 4 Probyme 1 Cus 3H, -C = CH oes Or ee ! Cx Cay hon 4ube i) Rcpic CHaraceR oF ALK ynet Mono Saturn ate ia e 1 1) ReacHon Witt Nanity’ | R-C=C-u NaN, — as R-C=Cnk \ en Scdommide ( wore) + 2Nig NC= Gry # Dwr —s Nee Cne + 29 | Cee | tf . ) Regetion, Ut Hn! onmmoenact RE=CH + Tee (rong) Ice — ReQSeEg NHC? 4 HS & 1 fear ‘ i TiC =ica +210 (00459, Jee! 5 E06 SF CCo BINH + TAD “ny Rencrter wo, Pe, 03 beet RC=CH FTAs (roy) Jneg —D RCECAS +-NiyNe, +NH ho= cH + LA (Ne) INQ > Bees es Petes ove Gttdtc mK makwe S R-CH= =c5 Hf. aking: webs” => Ree ene tNi, Laboratory Reboraton C0 + Spo—> Goth tcnecn eucty Lene | | Agovanc HY DROCA RBo IS | (ARenes) | =| The UWneerureted Hydvo Cuoows Cowalhlg OMe or yore Benzene Rng Oye UUM dyomntic Hydio Covbous . They aye abso Wrourm Aromer Avowotic CO ypounnals Com-+tadininng bomzome ey ane Arron os benz enolds amd dere not Coneding aye nOn- yy f STRUCTURE OF BENZENE / SK ee He i) Motecitay fovmmule yecomimends 4 be hig hty whaturveded but t+ es Very Stable Comboumd omdl behave vory AYA evant Ayrrn cLenes Od Mr sryas i) et Connect be represented by cbon—thaly, Strtepure becarue Amy obo chor. Comerpersling +o dormrute Cy, Lotte pescars double Omel S41bu bond and Sl mor pm Oe RERULES GSrRUcTURE wm 186s ues cape ) po structure d benqne Roneee the once of tus Kemetic 1,42- allot cbt SOR SI all cee cece bow cel Seremch ‘Shnjle bon However the) fact |i bergene ie ees me Ortho clisuibs teed doiwative . He oveytorne tHe problem by 2 Gveept + eealtaHtre are 4 dlethde; pends mr benzene , & & ey Hl) Keble ‘s Shurhive poscer veo dbpurlade bord Coleen te Since be 2Hmea weaclne aw eee a aa anaes i dee, not ce Odo Hoy Kenchews CON 1 ' ) ieeg Wil) The beret fevg-tn of, CC syle bend is IS4 pm end C-C cloubte bore 134 bro Kebabs Stricture pesceu | Hee Wwglt ond Her dot abe Mes bencene ing Shreuld wet be Uloy but 44] AXE Coes tae yes a bm - Explanation with HoT and eieieee. © Bemgene bs hy bid of varios retowa ting! t4wicture The ture Shushige, A anh R given by Kekule aye main’ Comtyibuting Abnuichue . The Civche Im, Benzene Yel ows Shy e- Urhtd, cre dehotalised btw 6 Carton clny O-6=6- 6 Oy Ae six ae Odors tn tonzeme Ore, Sh> hybridized . ALA ty) Tas! spe on en of Carh, Covboy, tow weep width Sp> hy bua ee of, edtaromnt ‘Corte, “ocho $0 fermn Stk Ce o bends Yn hexagonal plane in) pias Sh? hybicl ones ey whim ¢ ovplint of, Hydwogen olen de [orn Six CH & bends. | , iv) Each | Corben) atom ts mow! Lelt! ublln one Uhh bodice P evbtie® perterste + plone : v) Doren p cvot rat aye’ Cloye Crroush 40 for T boud by Perera ovemlob . Theye vt du Slew possiuitietes of {omy 3 TT bonds . 5 a VI) The Witevnurctoy distence btu atl Corben atoms In the lig bet been determined by X-vey clilvactton +> be Seme . Nil) The Sty deethed T-e- Com move freely VeUk Sis Civbene ouclet Ins tead of ony two bey mudtidey C K vill) Deloatssed mm e- Cloud te atnerted moe cranglyn) thon elecchon cod Ioblhed be hu (aoe Therefore bresene of Bele a Probe, | ci! J \ Grtetns Lower energy | mee gdeble an iny ponent Hopclabacbiene: (05 Coheed ty Located Ev eee \Rrommmeicry a fee : ® nm e- | present by He mint be ee ee } | 1 | i i i} @ Rog Shotld be! Coplemey @ Presenee of (Umt2) mn e7 Im vg whee om is hrtegen (Huthed fate) G) Hetevoeytle wry Cem ele! Shel arovbedtenn, HoH Sedtt. Here bee jabs DiRecriVE INRVENCE OF SuRsmrvenrs When a mone tubsHibed ‘derivative of boven el lic! subjected 40! : » fiordtney Subsriiuton ; the pesitten occupied by In tomnting Strbgerruerip | qrerp on yg prmentty cebends por neture of Subrrient ohyencky prorent- dm othey werd, Substirent Rbredy Present decieer fortrenity, +he pesitten +e be paken by / hacewdl is5 SUAS Hee Soup on te ng. 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