Organic chemistry of Aldehydes, ketones and carboxylic acids., Lecture notes of Chemistry

Download Organic chemistry of Aldehydes, ketones and carboxylic acids. and more Lecture notes Chemistry in PDF only on Docsity! ALDEHYDES, KETONES AND CARBOXYLIC ACIDS * Some Cosrboryl Compound, fee. © c (R-CHo) —- Shdabayelas =(out); Bo = 92. © F it ae CRetj—— Ketones Cone) E fo 7 ! Q Q << L _" u G (Q-(oon) ax Coobox ylic Cds i Trea N Goic acid) a = 8 Et cy } c_ CReor) > Cstens es - x = OR ALM yL at ecrrente) , t © a h vs G CRcosit.)\ 72 midy ma | Kv NH jraemmepeesp bet  ¥ Nonencenroes Oe Cragouvt Commons 7 Os pen tas seni — CHO 4 chs i 2 12. Bienattnys loutanal i a ee 6 Gite = (ieee 6 et « b fOr pentanoic ae idl ‘= =U — G4 sine Jae Ct ee Ci) Os Ore  -_—— 8 > (Fas der, saditenaar Bly 4 Carella -aBiinadegs ff a buse ushere ie Hae Carbon cass wo Mlowis atid | Qua: How & 2 w bonds pass " | Present > Cut-2ene t-al. 1 = a I . : io, Was bonds _ . i; Ho Clg CA = Cy Cah 4-9-7 wb | ' “ r (Quy ne (usry © & 1 bondy cy __prgent i) —— aaa 3 om LTA. a ge ara, Iu 6 bonds C - c{ al if Ptr bewily : = 6 ————— H° = a) ae Ee oe a 4 + ———_—— onan hogs ak dal deka tess Oe gee 4) By Rosentnunel Roa etiov c ‘ => In this xachon Acid —-chhowndlea LiKe _Benzey) — chtoride undagnes hydooo « po ae procree oh Palladium tnd B&O, totabyste +0 gfe lolahay des. ies -CL CHO 2. ; =e et —— in (J) Pd, BosOy — Lot. Era — Ben zallehyde Chimde i:  un Oy Chemie en ade tiie <2 pee >. Thy Seove don ve Sich em tee ater Wits Co 4 Hcl in Peence: Ain \ydnowa fier, Ond Cac cea iS te La Bitte. Bode yenceto- mp uid) | ab beset ot end sh Sa i Sai ds a 5 J eS a - COFFE CL pa Se et Ay ss Cee Go Benzene - = = — Bentaldeh y ce : Z 3. By Oxzoation fe Ai ptiades tte nev = Priecany. Atcetrola = Oxidation us Ha Sodium Oirhrromate » 2.4 we a Lace {fuss be =. i ee a ee ee “ot Co} BC RCH OH Ne ak = R-cHO NG, =o > R-Looy Ce ay 2 4 Ci? odvonat) Cone: Has0 Mdebydes Coe He60y os > Paiesensy, abesbinl, spstloris on pad pctinwts tient | Pace Ce a ainn Chloo ko gine wip Akeley agi 9! ; teed R- CoH papa R-CHo : ee ehes}ceh)——_— Atchehsy das. Sa Bs eicgaslag Wiltshire eereced Caulld BY Sednwa Aichknomere “And 44 Ow. LEO eG Ko tons, R ; pe efi ete denied ae R— cet ot Noz¢<70,/ Cont Es f= B a (> alee ot) — HeS0y- O = Keto ne ee (0 Cet, Coty ppp eT cst. -crip rast cme eo Eiharal 1 my —.- 5 ee ———tp yu Ak Oy = CHa to04 ee SS ae Zshowmsi © = —— Sets ie cal “ a er fod =: 7 Crt, Ort [SS Ohta CHO a Cam ole = 4 aay ee set a eee Tol pola . — tan et SD bes SC Gl b GINO Sere, [oar eek Oy os : 3 : By ‘Vanagepane == Sine Duss 1 Ai) JG sted ration)» (eesGrie44 sa a niet Ses z RA 7 oH Bax SE ae ae ee eh Sa \ ees = _ [Resear —i At eee sol leae | — SE —— 4 ipualmeelemelininicemlietaleeimdieimm ieee et Lt Dh lll  Bisa H —_ Leo 50 R-UrtO. 2: ; =) By me ob preter Carborng © Ac Pure Atetekeg day Vege a, Ketones ! By Fereort Cenexs (ise P| _ : Aruny de> i > * Crzcoa ee : on -HC Conant - —_—t ~ plengh ethrod-l-One s = Cheap eae ae p hysical Perf dp M\sayass fa Weroues D6 D-Bonina Point? The boiling point’ sh Aideydes 4 3 nd iominat oa hicks ae ane to Fons Bt HWedbuyonbors becauite Te “C=O. Quoup _polon__dnd thw tr Spony atkactive hoster : 7 The _briling — points Mdakyds 4 Kerovws 16 Sos 0s mmpau O_ ecyic acids © Mabel - becoine thor, gy hydro gen bondivg 19 Aldea ds or Kern baad oad > TW Ordow oh boiling poms a5 Hgcoeceil -CooH > =OH >» P-C R 2R=tip >? -oY — esdas 2 = fi. : Pons Revenge che pollousing UA ate TAC acadi mg Midler Sh theis. boiling CA Ut ce ee Cowernrty : H-Ve, Aaies thy ob Ncbelydey Qitd Retovie, etreares gt Hao 4 Ye incmae in no % Corrog Ooms ia thn AGP eho Tees ic Dec cone the Aric wp {C Rove polo ord — hydro phobic (1 Motwwe Be iorati ae fusl__Hetona ith Soluble. iG 7 Hy clroplobic no ae ing LiKe Se arciad,  PF (core 1) Dei “Due To %-HYorourd. 0) Dvvsa —Coninessarton 3 3 Ti Hs peacdian 2 ont oh “Nyon Retps stack to ta He praenee pf dilute, Atfols liake Naor hares «Beth eu, to awe Be Hydsoxy dah whack. is cobled At i B= Huds Potone which is cotled Lr bSbe Ded 4 rations 1 gine %- 6 unsotu ae ears aes Jaden Piro aT 2 CHy—CHt CH, “@ CHO, (hes), Foal dy [etry betened | SS —=HyD TTS OG oe Cet, CHE = mCENG  tones. 0 rida OL a EE P(t) Symime biicall Ketpvss > Symmonicat Ketoaa | Like Aremus undergoes Oxidation Usiroy | mihi ing Sbon9_o ike HNO — Hy804-4 Ky bs, OF pee. oO Gite MUxtwu 8 Kwa On 4:20 Cottudata alas Ky Ce, OF eg Ot tone Fg80G EHhanyic (1 ethadsic atte tO) o Popanere Creict acid A I CHycoord t FLO +4 C0, 1 Ethone iG aad. | (a) box usyemeterca Venus: box eS Cie) Contre Mo long Oxi dottoy) Poppyh duke a ze Lung Aco Vita New and io fox CasU60 © ppdb!s Ruto. The { pra cotioa Cow olotd. prod. wits sia Oe be the Compaowtd Mani hay Soo ah ‘re _Rotony Ou product vsill lee Ae Yorote rant Ay, Me Cage acid. will A Aus OL CastboxLs : Chg COOH +4 CH,CH, (00H Ettowrl © propel’ eid: quid  (v) “ollew’s 1 beste ss Ms heat oe : igaaenl nd ae wen. by — Wiplatic 3 Os== > Tews. 5 se , ert sedate - Cigessiy space eo golutio i: [figs + cer Soya pilen’s eogenk is ae Ut enr ands fe ormtad The poweetiod = = ~ RLoo” Se ~ athe, Suweog AG ae 2) mecnicen ING! Reb tet was “ess * mi et ob Midday de pour = Aisassipe ani née tus que Ss = big Z ves Bh sid u epee a Z Foug"® A ee ge : es oh ___golweiot of Sodium ott) TTo eer ke ie a ee Bee S233 we a ors  > Wen fehiin-A 4 Perling sa Gdoloodd J fe ts hu pr Rtas ‘lddebnycle ata) | We Mixtwu ic ig al oh 0 ane Obstcl - — =e Aan preretue, ph filiphertic ouldlchcles + 2-0 + Wk = + Sot Ss > Qo 4 Gr, Ob SHO | ; Jr sleek: Pad oy ipl tates } i) tn rr Hdd 4 Wie fe it) love Kestemer Renpitiset 8 Cine). ee a oat eo Corboayt compounds (ike as oe and Ketones seack sit apping KOH in prwente Ah Ethylene, Glytel ae AD Gite Hy dweorloo™ - (Cryo CH EO? chy Ot hn —ateliineh tH) Ae = EAleanal Atty Kho 1 HO A on Cot! $C 4G, ea g Ug As ii Enter Gly oe Ol, t 7 . AZ Proponene pC Lemmeruent veetiog : La 45s om tarbor Comgoucds like oe, xed UcuYU uaing VON, sale a CNL and Cone. Hcl m09iNe  ce ait ah Adaya Dihyobuc alralrely osu ts eh cyclic oteral and cyclic 7 Renetion — oh Aldalay ches — onal Mermaen es Dinky cout qicelol Ney A powmnoutino ty ey CAC Ovetal + cy hc Korot. (2 3 TS eaibvl tutes Place im presence cf, | toes HU 40a and PTS (Para Toluene Sulphonic Ou | CHa \ CHa —od Cre oa : ae HO ol ( ef, Scag | : CH, —od aes Chas =o Fihanal Frhon-l-2 dial Cy chic ocered: ct (c CH, ( Gra a liggett It ele OU eel et Ee Ss ) 4,6 ee CH, + Ae Peper te aac Wak We ; 3 ontinn eh gration Bh terol- onal - Ratad 46 0 yeveruibte aco-ttion Canal Aucuport th P reenle eh seser Wh fradic ual wo Cunolergoes hay dounlyss to_qive reodents loa ; ent  = — ‘Aldsiyda 4 Katona wiv Aram = [elke dwrivativ ea Cn ae Na { Sees = -. a Pasi fin sae Come) a AS ee Jat  (C) é z= SGaeek Ne ey Meats ; é “Sent base : (d) z=nn, / | es mighadtt ae a fi =o, : j ee ee “ety out (e) z= NH XO) f - Ns : Habeas 2s NH NH O) > Seen mt -{O) | 2 : as Se dail eager ag _* 02 (fier = 3 WO | So \ QOr fo =O +N Ho NH 40)-x0, ome Zely vibe plooyh s q ry drazivs ee e Gane NH OS 2 dwibo e Ehaleedieal O u (4) C= Me C= Ses 5 as = hi W - CaaS at oe thet / a eG - J : — a es es MA 9 Met venti aubawne)  . a : if tetrona Sodium bi gulpite Py ee ee L ae = CH, Orla : seek gets: oer Re ec Pc se fe Dll — nd Berd peed ay oI asa a4 + popanone L anit hag pecte— Sse lutte Prysinia . = ee SSE }—Preena bee ———— Se =e Vv s a Crt. coe CH. = 0,Nq —poparme fodium Bisulfie — VULEDOH TLIC. «thas L1J0N pac lhee Seer Finks HY OE = [mpostant —_ Poivts ats boo saad abi Te _dattivity 6b, Aides des and Ketones toons Nushoplitite.adalition rtoution 1 codlifjenent Te poe th Hyde ami aldsreyde ¢ makes wie MPs — pees Ketovies  *'@). The Corton a Corbongt — group dial 0 pari portiot positive Pee ee polor, Covalent bo 6. Ou fo the Positive Cherrge. eh Cosulon ato wo | The Auckoop ites OS, ROA atrhacted! wands tHe (otto _otonqg due polo Comland sh eon. > Het hors oso 2s Wuchooplalic _ addlitinw: > The sbuctiow eh Casooryf. group is planan 4 the cacttoon ob Carbonyt que ica ee > Onthe addition dh nucleophile. tres _ beematon ph Teha hednal ineumediate dada is Complete Qunaher ob 1 elechona of carbon eutora tp +e Om gen abowe_ands te tale Oy ly lesion th Carbon Changes bro Sp _to_ sp? os, ONY ON So SS (26 Se a C zt at <3 So a Sie aa Be SS 0 Oe Sp hyforch xa) se Terahedsod Pipa AS rea ~ Aidebuydles ond Matoray oe used’ hss preparatio i i ae compounds Lec aiken he Fes Ah solution oh: eras oe i vowsten is Cold ay formals ‘0 iS ued to Powe dua bodies + Bloc Specimen  iS_used _{j0s__gilven Polishing _ enzoldehi do (5 wed oO hlavowing agenr iA perbime indus Deegan = aa ieee i ie ee wna olourodl dhe Qe Ke Matlachste Fee Arete ts Used cy nNailpolish 3emover Ww used ay solvent i induabres,  Pee Eppes | dh election. “sediaying and eleeron Leithdrousiny —gaeies ov the acicl’ ty oh Cos fast yi C oc Oy. : iat cr) Ehyect ab Ayre dlomating gre ups: easy Nick eletpoyy devas prude — Rit ehpent nonce i+ psi ta incvease fra echo dunaity i the dH bond 1 & Yeloardioogh wH* tons Will toe _ MB bifid, ence Pomc 00d 1s Shonger acid vou _ Ocetic aed, Fousdher tf ebpect gl) alkyt apap induares im order, tH, SCH CHa Cots), CH < Ctra), C os Hence the - elodive- ch nethe Can tori ¢ tide will be “oa = = ; UH, WOH > Crt, CH, COOH >. CoH; )e Ct pol s[cH)g tooth Gh Etheck th Quen wsitdoaeitg — Atoup. > _BYRO Electron __ i Padaguain oot ebpeur _Ond tt decacores Ywrotl SES Ht >= BPS Ply. do tae Arength- oly the Cortoosytc ait, sill be ay A SD ECC Loot!) > ACH Looe Se Cty coo > TCH, COOH > Further, Quoc en Pra Aourlger. 6h eheeboa voi © Gots Shion — pxill be the QddiG shuns th. > Fro Cl, Coos UPtoon Soe The wduuive abbect lee set napridly —usi tty magionce, 8 auidic_ rena 05  oe or — == : (oes f aan ahGidy Ciafac t= > ChtsCH = CAs Carott th. Ctaasithy Pest. “is cleavage. ef 4 4 H Bond © Renetion suai) Bore —Cotmote i: a. +90! ———s Sate + ee £2: R=coon. atc eNlabH => RA Coola: ttt On PCy Coo + NooH Se lt peck 3 20, ree Re > Ragetion ithe motoly: fled + metal —= Satt 4 dik laogen: =e HONG | See 2 nla — R-coonla. ati Heep CH atm att iy - igeaonta se ieee: S. ee Aeetic. 2 CH, onta 4+ 4,0 + CO, .  + Roaetions Wvotuing — cleanege Sh C04 Round - (0) Fosraation oh eid Chtoricles * —S wz oy 3 CH= C—O Prk, BH, CO. 4 HPD, ee tet j Oo Cht= C—O Pt lott se Oris patie Hoke. St S vg 3 © << ex Ort. + SOU, Gt HiGLoMso A etch: 8 . (b) Formation eh. acid — t , Q-¢ i R- = OF 4 RC -0H 5 5 POs aes SH)... tl f@ : a ete Ee t z ne Coot a — on 8 oe etic ef pi2 ~S) ae Acid aig, 7H. CH - | @ Strong | Alexie ©) Formation sh Bote! [Acvd >ot 2 Atehels A] Cont—HySS - R-cooH + R-OH: a R-cook