Organic Chemistry of Phenols and Ether, Lecture notes of Chemistry

Download Organic Chemistry of Phenols and Ether and more Lecture notes Chemistry in PDF only on Docsity! _/ PHENOLS AND ETHER. a lL HENULS. + Cutie th Phenols * 1) Fom Genzare dia Sulphonic aeid » SOs s __ 64 5 2 ¢ a afi Nec SO; nent pusion Phone. — Sulpbowi c “jad 2) Kom ae _ 3 Tn the prove) _ ite th Rontens and) opens _is hreatecl Ot S23K fn a clesed vene) ia _pruence qh phorpheric oid CH; P04) to bora Cumone On Pan Cty 10 Wide oh CUM ond Sy Bguenw’s odin Conbonate Sotvdion 1G Lryperowide 4S fosmed by Oxidation + Thun i4_ is darted ith — dilute Sulphunse aid) in babel pronst aural pane oe . = cy ff CH, - = 7 oo faseod _fis(0,) Soe a 52K Ty oq? oq: Corns Ben unt ae NaC, ex : a - : ayaa 1 [Olas cae Phondl H2\0,  eurtwre eh Ji d y Aguwous olution 0h Socdiuco lydowxicle is Incatedd iv a clossed veel atk 300 bar Peeopurne cund 633K koresatwre Onol Oo peste na Sodium SHU sb Planol Produced Or — ken wiagickt: fired ——_——] i tote Owoduet WS wedeesteal ei \  | OR-cn04 4 Na,t0,° — > > 2Reoona + wet + | — mW = tes a Pacenemaos ae vee ro tstee OW NV crag, 4 Ta absent th Mang ch chilevide fet aS ONY ide ton be urea. re  te ee oe —— Bub Trimerd Pe efits sy, (Aneel ; ate nee On 0 = od Fa Cott: Hay + Sa O Toate 4m > eo (6) } 4 hep = 8 -atiho aia aj} apa p- Nite p PP to Pernt oh WUming TWO, oS as > fueung 4 cone Soh nee SSS ee L RE O QU G Trnibo 4 _—_ 5. : phonet a ; [Picbic oe tir) —- ' 7  — SAP lt a fesse edamedlleediu [Pacparcation th Phang erent) ol Ole == ; : — = tered | ——_ $7 Tae {Opus Ret neon [OF ae = : - - Ns fe <peiencs 1 bg z reHge© ch Naor — ots o—— —— = toc tt ee = a Ie  a ae an ? Keocraen =e AIS > Tn Ais de tion , _plaon oh fui new worthy. lon Noon goludion ine Socdituno. Pls moxie peachy = Seen cyst Conlon lo Yidte ie, uot uddaicly _: Jord pes. steoiciang prac hollowed! i = acidic 3 hydretysrs 5 SLs d-Hyduxe | Qenzwic, “aud Commo aly pagent OD. Ss, Sotig lic rare ona toon = Oh an = -Coor} CooNa ae od - eed a ae - Vaud : : root Chem er eet} ees. 0 = ae et Z Lo 7 tig == hii po acd se : 5  5 = Ciesaeee : Oe Died. = OA Oreiclotio n > O N tro Cry Oz 5 4 Cont: Hz SO, Cytto "Newb DS diend! fry ct one — Cen eo quinoa) Gon 3 Fie = i) Acidity ab. phenol “ier cme “+40 -aleatsl R bs Wik Short rok on Adie not th Prenat: lg sth e — Te _Plunevide iol 1 Plomals is Stalotlize by “Reronone he 03 Resonance 1G | ‘ Qhsen ta Airehety. > _Moelecula ha wiv SMovlante GILL abo duiding in NEw a0 Pharcat! Phenericl = a) on Seat R83 oD  . ity ob __phenaly Sates pe Ke CH, se, pe Cort Bling) “lector, seal ens ing ee z SO: cee ond bene Bc 4252 ye &  Chas: Which eh the (Lowi “| a hobicle 8 ee voi lh <2 Synturi most eavily 9 (a) 9 - 2 bocd Pwpane (b) N-@ Bromide () 2-Bwro butane (- Mathyl’ Bromide (Cg ev) | (¢) Gs . Ch C— CR by ws! ,; (b). Git, “Ut C gC, iar CoP) iil. 7 Cy _ Og CH cH eg), C : br ‘7 Increasing Gielen = Ss asc < bed. o | as By PiraiGous > Alrolrel tunalercqoes leh bration uit done. “Hy $0, CUBR tenupretre 10 ine Ethwr and Tt also Shows dehydration Oh Gash deep seetoie to. give AMen, This 1S 4ewrpraiwe —dlependant —dea-ctro)- CORc- H2S0, id OCH Cel “OH aye? Cete-CHt, —O —CH-CH Pthanel. ie Ether Chere Cont: H28 Cte Cttg =O ae PC Ce fhansl, =o ip tenes :  roo H pigs 3 dun titer ta St ee oy Bee hs) a pi places a 2s = Fas r= ao CH Ut SO CH tite dt yt | éthoxry = S SS ds lan2 = uaa aa > LSD = A Rockogk e : — = E . [oe 4 EES tA . Pay aCtlp~ 08 crigcets B20 a Chal tO Ct CH os i ‘al J + 4-04 4 ee ih, pls + 969 be  Cee ke O: — 5 th teetlels and Pou “ow “Foncionad eae Troma. e esti 4$ Mettey MU tro CG gor) Ceit,-6 -cHt,) Buen trough _ Acobrel 4+ Eftronds sw __ iced Onol thoy is Same cretecubt may tw Boiling pole oh Teorels is Grater ds Comtpardid to Caan =! eS BY Tis 5 _ due to. Interereleadan _hydrogec Ronding — praent 19 AL cohab. | 2) Te Boil ing, poit+ hy Fthour inertone: vit yp ltreoxe in > theix meleculor Wan. : : cS & 8) thor wrelerds cor Soluble in woator become Lone he. ctoiiky fo bore Hy d%to gon ond wettla wd dens + Qomnicot — Propertien oh, tues * (i) o talaas ust) Loosen (biden as \ i tt Ciy-Crt)—O= Cop CH SSeS ia 2H CH OH Chor -Eihaae Medios Piha apts a ae With Hydrogen _Hadicler .: = errs Seti er « Rx