Primary, Secondary, Tertiary, Quaternary in Organic Chemistry, Lecture notes of Organic Chemistry

Download Primary, Secondary, Tertiary, Quaternary in Organic Chemistry and more Lecture notes Organic Chemistry in PDF only on Docsity! Primary, Secondary, Tertiary, Quaternary in Organic Chemistry  Primary carbons, are carbons attached to one other carbon. (Hydrogens – although usually 3 in number in this case – are ignored in this terminology, as we shall see).  Secondary carbons are attached to two other carbons.  Tertiary carbons are attached to three other carbons.  Finally, quaternary carbons are attached to four other carbons. You can’t go higher than that. To have five substitutents, you’d need 10 electrons around carbon, a clear violation of the octet rule. CH3- = metile -CH2- = metilene -CH- = metino | We use the same terminology for carbocations. A primary carbocation is attached to one other carbon, a secondary to two, and a tertiary to three. You can’t have a quaternary carbocation without violating the octet rule either! NO! Alcohols also follow the primary/secondary/tertiary nomenclature. The rule for alcohols is that they are named according to the number of carbons attached to the carbon bearing the hydroxyl group: in other words, whether the hydroxyl bound to a primary, secondary, or tertiary carbon. You can’t have a quaternary alcohol – again, that would involve breaking the octet rule. [A bit of non-essential nomenclature: the carbon attached to the OH is sometimes referred to as the “carbinol” carbon]. A related category of compounds are the alkyl halides. The naming for alkyl halides is similar to that for alcohols: they are named according to the number of carbons attached to the halogen, where halogen is fluorine, chlorine, bromine, or iodine.