Alkenes and Alkynes: Classification, Nomenclature, Properties, and Reactions, Assignments of Organic Chemistry

Download Alkenes and Alkynes: Classification, Nomenclature, Properties, and Reactions and more Assignments Organic Chemistry in PDF only on Docsity! Chapter 3 Alkenes and Alkynes CHEM 2300 Spring 2003 Skip Sections 3.11, 3.12, and 3.15b Reading Topic Problems Sec. 3.1 Classification 2 Sec. 3.2 Nomenclature IUPAC and Common Names 3, 5, 35 Sec. 3.3 Facts about Double Bonds geometry, bond lengths, rotation Sec. 3.4 Orbital Model of C=C, pi Bond VSEPR, Hybrid orbitals Explanation of properties 7 Sec. 3.5 Cis-trans Isomerism 6, 34gh Sec. 3.18 Facts about Triple Bonds Sec. 3.19 Orbital Model Triple Bonds page 71 Physical properties Chemical Properties Sec. 3.6 Addition Reactions Sec. 3.14 Addn of H2 21 Sec. 3.7a Addn of Halogens 8 Sec. 3.7b Addn of H2O 9 Sec. 3.7c Addn of Acids 10 Sec. 3.8 Markovnikov’s Rule 11, 42a-d,g Sec. 3.9 Mechanism of Electrophilic Addn nucleophile, electrophile mechanism with HCl, H2O carbocations/stability 13, 14 Sec. 3.10 Markovnikov’s Rule Explained 15, 46 Sec. 3.15a (skip b) Additions to Conjugated Systems allyl cation, mechanism 22, 23, 24, 42e Other Addition Reactions Sec. 3.13 Hydroboration-Oxidation 19, 20, 54 Sec. 3.17 Oxidation: KMnO4 and Ozone 27, 56 Review of Reactions 59 Free Radical Addns: Polymerization Sec. 3.16 Equation, Mechanism, Examples Triple Bonds Sec. 3.20 Addition Reactions 29, 42f Sec. 3.21 Acidity 32, 57